1,1′,1″-(1,3,5-triazinane-1,3,5-triyl)tris(3-(2,3-dihydroxypropylthio)propan-1-one) | 1123041-92-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 三嗪烷类
• 英文名称: 1,1′,1″-(1,3,5-triazinane-1,3,5-triyl)tris(3-(2,3-dihydroxypropylthio)propan-1-one)
• 英文别名: trisdiol；1,1',1''-(1,3,5-triazinane-1,3,5-triyl)tris(3-(2,3-dihydroxypropylhio)propan-1-one)；1,1',1''-(1,3,5-triazinane-1,3,5-triyl)tris(3-(2,3-dihydroxypropylthio)propan-1-one)；1-[3,5-Bis[3-(2,3-dihydroxypropylsulfanyl)propanoyl]-1,3,5-triazinan-1-yl]-3-(2,3-dihydroxypropylsulfanyl)propan-1-one；1-[3,5-bis[3-(2,3-dihydroxypropylsulfanyl)propanoyl]-1,3,5-triazinan-1-yl]-3-(2,3-dihydroxypropylsulfanyl)propan-1-one
• CAS: 1123041-92-8
• 化学式: C₂₁H₃₉N₃O₉S₃
• 分子量: 573.753
• InChiKey: WROJRLYRNPEHOM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -3.4
• 重原子数：
  36
• 可旋转键数：
  18
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.86
• 拓扑面积：
  258
• 氢给体数：
  6
• 氢受体数：
  12

反应信息

• 作为产物：
  描述：

  1-硫代甘油 、 1,3,5-三丙烯酰基六氢-1,3,5-三嗪 以 甲醇 为溶剂， 反应 0.25h， 以79.7%的产率得到1,1′,1″-(1,3,5-triazinane-1,3,5-triyl)tris(3-(2,3-dihydroxypropylthio)propan-1-one)
  参考文献：
  名称：

  机械坚固，自我Healable，高伸缩的“生活”交联聚氨酯基础上可逆ç ？C债券

  摘要：

  由可逆共价键构建的刺激响应性聚合物具有不平衡的机械性能。在此，合成了一种含有芳香族频哪醇作为新型可逆CC键提供剂的交联聚氨酯，其拉伸强度和破坏应变可分别从27.3 MPa调节至115.2 MPa和324％至1501％。作为C相对高的键能频哪醇的C键以及硬链段和半结晶软链段之间的氢键。此外，频哪醇的动态平衡可实现聚合物的自我修复和循环利用。有趣的是，大分子之间的动态交换首次成功地与适用于热塑性塑料的固态拉伸相配合，实现了热固性的增强。同时，源自频哪醇溶解的自由基可反复引发乙烯基单体的聚合。这项工作的丰硕成果可能会创造出一系列有希望的新技术。

  DOI：

  10.1002/adfm.201706050

文献信息

• Thiol-ene reactions of 1,3,5-triacryloylhexahydro-1,3,5-triazine (TAT): facile access to functional tripodal thioethers
  作者：Chinwon Rim、Lauren J. Lahey、Vijita G. Patel、Hongming Zhang、David Y. Son

  DOI：10.1016/j.tetlet.2008.11.094

  日期：2009.2

  Efficient syntheses of tripodal thioethers have been achieved by ionic thiol-ene reactions of 1,3,5-triacryloylhexahydro-1,3,5-triazine (TAT) with a variety of commercially available thiols. The reactions are complete within minutes and give the products in high yields (63-96%) and high purity without a complex workup. The thiol-ene reactions tolerate a wide range of functionality, including hydroxy, amino, carboxylate, and trimethoxylsilyl groups. The amino acid cysteine is also an excellent substrate for this reaction. (C) 2008 Elsevier Ltd. All rights reserved.
• Dynamic-Covalent Macromolecular Stars with Boronic Ester Linkages
  作者：Abhijeet P. Bapat、Debashish Roy、Jacob G. Ray、Daniel A. Savin、Brent S. Sumerlin

  DOI：10.1021/ja207005z

  日期：2011.12.14

  Macromolecular stars containing reversible boronic ester linkages were prepared by an arm-first approach by reacting well-defined boronic acid-containing block copolymers with multifunctional 1,2/1,3-diols. Homopolymers of 3-acrylamidophenylboronic acid (APBA) formed macroscopic dynamic-covalent networks when cross-linked with multifunctional diols. On the other hand, adding the diol cross-linkers to block copolymers of poly(N,N-dimethylacrylamide (PDMA))b-poly(APBA) led to nanosized multiarm stars with boronic ester cores and PDMA coronas. The assembly of the stars under a variety of conditions was considered. The dynamic-covalent nature of the boronic ester cross-links allowed the stars to reconfigure their covalent structure in the presence of monofunctional diols that competed for bonding with the boronic acid component. Therefore, the stars could be induced to dissociate via competitive exchange reactions. The star formation-dissociation process was shown to be repeatable over multiple cycles.
• Mechanically Robust, Self-Healable, and Highly Stretchable “Living” Crosslinked Polyurethane Based on a Reversible CC Bond
  作者：Ze Ping Zhang、Min Zhi Rong、Ming Qiu Zhang

  DOI：10.1002/adfm.201706050

  日期：2018.3

  pinacol enables self‐healing and recycling of the polymer. Interestingly, the dynamic exchange among macromolecules, for the first time, successfully cooperates with solid‐state drawing that applies to thermoplastics, realizing strengthening of thermoset. Meanwhile, the radicals derived from homolysis of pinacol can repeatedly initiate polymerization of vinyl monomers. The fruitful outcomes of this

  由可逆共价键构建的刺激响应性聚合物具有不平衡的机械性能。在此，合成了一种含有芳香族频哪醇作为新型可逆CC键提供剂的交联聚氨酯，其拉伸强度和破坏应变可分别从27.3 MPa调节至115.2 MPa和324％至1501％。作为C相对高的键能频哪醇的C键以及硬链段和半结晶软链段之间的氢键。此外，频哪醇的动态平衡可实现聚合物的自我修复和循环利用。有趣的是，大分子之间的动态交换首次成功地与适用于热塑性塑料的固态拉伸相配合，实现了热固性的增强。同时，源自频哪醇溶解的自由基可反复引发乙烯基单体的聚合。这项工作的丰硕成果可能会创造出一系列有希望的新技术。