Pd(N,N-dimethylbenzylamine-C(2),N)(N-acetyl-α,β-dehydroalaninate-N,O) | 166408-99-7

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: Pd(N,N-dimethylbenzylamine-C(2),N)(N-acetyl-α,β-dehydroalaninate-N,O)
• CAS: 166408-99-7
• 化学式: C₁₄H₁₈N₂O₃Pd
• 分子量: 368.729
• InChiKey: VTXFINGAASHFNT-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  Pd(2-(dimethylaminomethyl)phenyl-C(1),N)(acetylacetonate) 、 2-乙酰氨基丙烯酸 以 甲醇 为溶剂， 以82%的产率得到Pd(N,N-dimethylbenzylamine-C(2),N)(N-acetyl-α,β-dehydroalaninate-N,O)
  参考文献：
  名称：

  Metal complexes of biologically important ligands: Synthesis of amino acidato complexes of PdII containing a C,N-cyclometallated group as an ancillary ligand

  摘要：

  New amino acidato complexes of Pd-II of stoichiometry [Pd(C-N)(Aa)](C-N = C,N-cyclometallated ligand, Aa = N,O-amino acidato ligand) have been obtained by reaction of [Pd(C-N)(acac)] (C-N = N,N-dimethylbenzylamine-C-2,N (dmba) (1) or N,N-dimethyl(S-alpha-phenylethyl)amine-C-2,N (S-dmphea) (2)) with glycine, chiral amino acids (alanine, phenylalanine and valine), and amino acid derivatives (N-acetylglycine and N-acetyl-alpha,beta-dehydroalanine) in MeOH. The compounds are characterized by IR, H-1 and C-13 NMR. The geometry of these complexes has been unambiguously determined by NOE difference experiments and NOESY measurements.

  DOI：

  10.1016/0022-328x(94)05204-o