Bicyclodecyl-diol-(1,1') | 102464-46-0

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: Bicyclodecyl-diol-(1,1')
• 英文别名: 1-(1-Hydroxycyclodecyl)cyclodecan-1-ol
• CAS: 102464-46-0
• 化学式: C₂₀H₃₈O₂
• 分子量: 310.521
• InChiKey: MTWRKHYLTMNKPA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.4
• 重原子数：
  22
• 可旋转键数：
  1
• 环数：
  2.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  40.5
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  Bicyclodecyl-diol-(1,1') 在 吡啶 、 三氯氧磷 作用下， 生成 1,2,3,4,5,6,7,8,8a,8b,9,14a,14b,15,16,17,18,19,20,21,22-Docosahydro-dicyclodecaanthracen-dion-(9,14)
  参考文献：
  名称：

  295.脂环研究。第十七部分。双环癸-1-烯的制备及反应

  摘要：

  DOI：

  10.1039/jr9610001512
• 作为产物：
  描述：

  环癸酮 在 氢化铝 、 mercury dichloride 作用下， 生成 Bicyclodecyl-diol-(1,1')
  参考文献：
  名称：

  295.脂环研究。第十七部分。双环癸-1-烯的制备及反应

  摘要：

  DOI：

  10.1039/jr9610001512

文献信息

• [EN] PROCESS FOR THE PREPARATION OF AN ALLY ALKYL EHTER BY CATALYTIC ALLYATION<br/>[FR] PROCÉDÉ DE PRÉPARATION D'UN ALLYL ARYL ÉTHER PAR ALLYLATION CATALYTIQUE
  申请人：RESOLUTION RES NEDERLAND BV

  公开号：WO2010086139A1

  公开（公告）日：2010-08-05

  The invention provides a process for the preparation of an allyl alkyl ether comprising the allylation of an aliphatic hydroxyl containing compound with an allyl source in the presence of a catalyst, wherein the catalyst is a transition metal complex with a phosphine ligand, wherein the allylation is carried out in the presence of an acid in an amount of at least 0.1 mol% calculated on the aliphatic hydroxyl containing compound. This invention further provides a process for the preparation of epoxy resins wherein as intermediate use is made of the allyl alkyl ethers prepared by the process of the invention.

  该发明提供了一种制备烯丙基烷基醚的过程，包括将含有脂肪族羟基的化合物与烯丙基源在催化剂存在下进行烯丙基化反应，其中催化剂是含有膦配体的过渡金属配合物，其中烯丙基化反应在存在酸的情况下进行，酸的用量至少为脂肪族羟基含有化合物的0.1 mol％。该发明还提供了一种环氧树脂的制备方法，其中利用了通过该发明的过程制备的烯丙基烷基醚作为中间体。
• Process for the preparation of an allyl alkyl ether by catalyic allylation
  申请人：Hexion Specialty Chemicals Research Belgium S.A.

  公开号：EP2213644A1

  公开（公告）日：2010-08-04

  The invention provides a process for the preparation of an allyl alkyl ether comprising the allylation of an aliphatic hydroxyl containing compound with an allyl source in the presence of a catalyst, wherein the catalyst is a transition metal complex with a phosphine ligand, wherein the allylation is carried out in the presence of an acid in an amount of at least 0.1 mol% calculated on the aliphatic hydroxyl containing compound. This invention further provides a process for the preparation of epoxy resins wherein as intermediate use is made of the allyl alkyl ethers prepared by the process of the invention.

  本发明提供了一种制备烯丙基烷基醚的工艺，该工艺包括在催化剂存在下，将含脂肪族羟基的化合物与烯丙基源进行烯丙基化反应，其中催化剂为带有膦配位体的过渡金属络合物，烯丙基化反应在酸存在下进行，酸的用量以含脂肪族羟基的化合物计算至少为0.1摩尔％。 本发明进一步提供了一种制备环氧树脂的工艺，其中使用了本发明工艺制备的烯丙基烷基醚作为中间体。
• PROCESS FOR THE PREPARATION OF AN ALLY ALKYL EHTER BY CATALYTIC ALLYATION
  申请人：Momentive Specialty Chemicals Research Belgium S.A.

  公开号：EP2393767A1

  公开（公告）日：2011-12-14
• PROCESS FOR THE PREPARATION OF AN ALLYL ALKYL ETHER BY CATALYTIC ALLYLATION
  申请人：Postma Ron

  公开号：US20120190811A1

  公开（公告）日：2012-07-26

  The invention provides a process for the preparation of an allyl alkyl ether comprising the allylation of an aliphatic hydroxyl containing compound with an allyl source in the presence of a catalyst, wherein the catalyst is a transition metal complex with a phosphine ligand, wherein the allylation is carried out in the presence of an acid in an amount of at least 0.1 mol % calculated on the aliphatic hydroxyl containing compound. This invention further provides a process for the preparation of epoxy resins wherein as intermediate use is made of the allyl alkyl ethers prepared by the process of the invention.