[Mn(1,2-di(imino-4'-antipyrinyl)ethane)(ClO4)2] | 381228-62-2

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 唑类
• 英文名称: [Mn(1,2-di(imino-4'-antipyrinyl)ethane)(ClO4)2]
• CAS: 381228-62-2
• 化学式: C₂₄H₂₄Cl₂MnN₆O₁₀
• 分子量: 682.333
• InChiKey: HQQVFNLLAZXORW-OXBZONAHSA-L

反应信息

• 作为产物：
  描述：

  manganese(II) perchlorate hexahydrate 、 1,2-(diimino-4'-antipyrinyl)ethane 以 丙酮 为溶剂， 以91%的产率得到[Mn(1,2-di(imino-4'-antipyrinyl)ethane)(ClO4)2]
  参考文献：
  名称：

  MANGANESE(II) COMPLEXES OF 1,2-DI(IMINO-4′-ANTIPYRINYL)ETHANE

  摘要：

  Manganese(IT) complexes of the Schiff base 1,2-di(imino-4 ' -antipyrinyl)-ethane (GA) have been synthesized and characterized by elemental analyses, electrical conductance in non-aqueous solvents, infrared and electronic spectra as well as magnetic susceptibility measurements. The complexes have the general formulae [Mn(GA)X-2] (X = ClO4, NO3, Cl, Br or I). GA acts as a neutral tetradentate ligand coordinating through both carbonyl oxygens and both azomethine nitrogens. Both anions are coordinated to the metal ion and the perchlorate as well as nitrate ions are monodentate. A high-spin octahedral geometry is assigned around Mn(II) in all of these complexes.

  DOI：

  10.1081/sim-100106861