propenoic acid cyclohexylmethyl ester | 16868-15-8

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: propenoic acid cyclohexylmethyl ester
• 英文别名: acrylic acid cyclohexylmethyl ester；cyclohexylmethyl propenoate；Cyclohexylmethyl Acrylate；Cyclohexyl methylacrylate；cyclohexylmethyl prop-2-enoate
• CAS: 16868-15-8
• 化学式: C₁₀H₁₆O₂
• 分子量: 168.236
• InChiKey: FIMUXQLLGBMSAI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.1
• 重原子数：
  12
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.7
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  propenoic acid cyclohexylmethyl ester 、 乙酸烯丙酯 在 silver hexafluoroantimonate 、 [ruthenium(II)(η⁶-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]₂ 、 copper(II) acetate monohydrate 作用下， 以 1,2-二氯乙烷 为溶剂， 反应 16.0h， 以80%的产率得到
  参考文献：
  名称：

  钌催化烯丙基硅烷/酯与烯烃的sp3 C–H活化：有效获得官能化的1,3-二烯

  摘要：

  通过异构化，然后进行C（烯丙基）–H活化，开发了Ru催化的烯丙基硅烷和烯丙基酯与活化烯烃的氧化偶联，从而以优异的收率有效地获得立体定义的1,3-二烯。温和的反应条件，较便宜的催化剂以及出色的区域选择性和非对映选择性确保了反应的普遍性。此外，该反应的独特能力通过进行Diels-Alder反应得到说明，高度官能化的环己烯酮和哌啶的对映选择性合成以及最终的合成效用是通过有效合成抗真菌药去甲肾上腺皮质激素而进一步证明的。

  DOI：

  10.1039/d0sc06845d

文献信息

• Process for producing hydroxyl group-containing vinyl compound
  申请人：FUJIFILM Corporation

  公开号：EP1832571A1

  公开（公告）日：2007-09-12

  A process for producing a hydroxyl group-containing vinyl compound, the process comprising: reacting an acrylate compound and an aldehyde-based compound in a presence of a tertiary amine compound and water in a reaction solution to produce a hydroxyl group-containing vinyl compound, wherein the reaction is performed by adding an inorganic salt of a Group 1 or 2 metal of Periodic Table to the reaction solution.

  生产含羟基乙烯化合物的方法，包括：在反应溶液中，通过在存在三级胺化合物和水的情况下，将丙烯酸酯化合物和醛基化合物反应，以产生含羟基乙烯化合物，其中通过向反应溶液中添加周期表中1组或2组金属的无机盐来进行反应。
• ALPHA-SUBSTITUTED ACRYLATE ESTERS, COMPOSITION CONTAINING THEREOF, AND METHOD FOR PRODUCING THOSE
  申请人：Kawamoto Takahiro

  公开号：US20130072712A1

  公开（公告）日：2013-03-21

  A method for producing α-substituted acrylate esters is provided which can be suitably used as an industrial method for producing α-substituted acrylate esters because the method does not have problems of apparatus corrosion or does not require waste detoxification and allows reaction in a short time with high yield. The method for producing an α-substituted acrylate ester includes a step of carrying out a reaction of a compound having a specific structure and an active hydrogen-containing compound under a condition where a tertiary amine and an acid and/or a salt thereof coexist.

  提供了一种生产α-取代丙烯酸酯的方法，该方法可适当用作工业生产α-取代丙烯酸酯的方法，因为该方法不存在设备腐蚀问题或不需要废物解毒，并允许在短时间内高产率反应。生产α-取代丙烯酸酯的方法包括在三级胺和酸和/或其盐共存的条件下，进行具有特定结构和含有活性氢的化合物的反应的步骤。
• Hot melt adhesives containing a novel adhesive additive
  申请人：H.B. FULLER LICENSING & FINANCING, INC.

  公开号：EP0234710A2

  公开（公告）日：1987-09-02

  The adhesive properties of a hot melt adhesive, comprising a base polymer and a tackifying resin, can be improved by introducing into the hot melt adhesive an epoxy adduct comprising the reaction product between a compound such as a polymer having at least one active hydrogen and an epoxy compound.

  通过在热熔胶中加入环氧加合物，可改善由基础聚合物和增粘树脂组成的热熔胶的粘合性能，环氧加合物是一种化合物，如至少有一个活性氢的聚合物和环氧化合物的反应产物。
• Radiation curable cladding compositions
  申请人：MINNESOTA MINING AND MANUFACTURING COMPANY

  公开号：EP0425305A2

  公开（公告）日：1991-05-02

  Novel optical fiber cladding compositions containing fluorinated acrylamide monomers are described. The claddings are liquids at room temperature which possess excellent coating viscosities in the pre-polymerized state and are polymerized by actinic radiation.

  本文描述了含有氟化丙烯酰胺单体的新型光纤包层组合物。这种包层在室温下为液体，在预聚合状态下具有极佳的涂层粘度，并可通过光辐射聚合。
• Method and apparatus for continuous hardening of visible light-curing resins
  申请人：JAPAN INSTITUTE OF ADVANCED DENTISTRY

  公开号：EP0420369A2

  公开（公告）日：1991-04-03

  A method and an apparatus for continuously hardening visible-light-curing resins are disclaimed. An object (10), such as an orthodontic bracket, made of visible-light-curing resins, is carried on a conveyor (2) past a row of halogen lamps (1), and sensors (6) detect the temperature in zones of the row whereby controllers (7) activate cooling fans (5) to maintain the temperature in each zone. The objects are moved continuously, either in a non-stop or intermittent manner, and deep uniform hardening is achieved.

  本发明公开了一种连续硬化可见光固化树脂的方法和设备。 由可见光固化树脂制成的物体（10），如牙齿矫正托架，在传送带（2）上经过一排卤素灯（1），传感器（6）检测该排区域的温度，控制器（7）启动冷却风扇（5）以保持每个区域的温度。物体以不停或间歇的方式连续移动，实现深度均匀硬化。