(E,E)-C6H8(CHCOMe)2 | 1228184-04-0

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: (E,E)-C6H8(CHCOMe)2
• CAS: 1228184-04-0
• 化学式: C₁₂H₁₆O₂
• 分子量: 192.258
• InChiKey: UXRKGVFVQZPUBO-MKICQXMISA-N

反应信息

• 作为反应物：
  描述：

  bis(1,5-cyclooctadiene)nickel (0) 、 (E,E)-C6H8(CHCOMe)2 、 三环己基膦 以 benzene-d6 为溶剂， 生成
  参考文献：
  名称：

  [3 + 3] Cyclodimerization of Methylenecyclopropanes: Stoichiometric and Catalytic Reactions of Nickel(0) with Electron-Deficient Alkylidenecyclopropanes

  摘要：

  Stoichiometric treatment of Ni(cod)(2) with ethyl cyclopropylideneacetate (ECPA) in the presence of PCy3 resulted in an unpredicted formation of a Ni(0) complex bearing an (E,E)-1,2-bis(exo-alkylidene)cyclohexane ligand, which stemmed from the [3 + 3] cyclodimerization of ECPA. The reaction could be expanded to a Ni(0)-catalyzed [3 + 3] cyclodimerization reaction of ester-substituted methylenecyclopropanes, giving the corresponding cyclohexane derivatives in excellent yields.

  DOI：

  10.1021/om100317y