[Pd(η(3)-CH2C(OCH2OCH3)CH2)(.mu-Cl)]2 | 164222-38-2

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 乙烯基卤化物
• 英文名称: [Pd(η(3)-CH2C(OCH2OCH3)CH2)(.mu-Cl)]2
• 英文别名: chloropalladium(1+);2-(methoxymethoxy)prop-1-ene
• CAS: 164222-38-2
• 化学式: C₁₀H₁₈Cl₂O₄Pd₂
• 分子量: 485.997
• InChiKey: AATRSTKQRPGERJ-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [Pd(η(3)-CH2C(OCH2OCH3)CH2)(.mu-Cl)]2 、 三苯基膦 在 KOH 作用下， 以 四氢呋喃 、 异丙醇 为溶剂， 以78%的产率得到Pd(η(2)-CH2C(O)CH2)(PPh3)2
  参考文献：
  名称：

  （氧二亚甲基甲烷）钯和铂配合物的结构研究

  摘要：

  Structures of (oxodimethylenemethane)palladium and -platinum complexes in solution and in crystalline states were investigated by H-1 NMR, IR, and X-ray crystallographical analyses. The following features are disclosed: the structures consisted of contributions from pi-allylic and metallacyclobutanone canonical forms; the palladium complex has a larger contribution of pi-allylic character than the platinum complex in both states; the degree of contribution of pi-allylic character increased upon the increment of solvent polarity and the addition of protic solvent.

  DOI：

  10.1021/om00005a060
• 作为产物：
  描述：

  tris(dibenzylideneacetone)dipalladium(0) * CHCl3 、 2-(氯甲基)-3,5-二氧杂-1-己烯 以 丙酮 为溶剂， 以82%的产率得到[Pd(η(3)-CH2C(OCH2OCH3)CH2)(.mu-Cl)]2
  参考文献：
  名称：

  （氧二亚甲基甲烷）钯和铂配合物的结构研究

  摘要：

  Structures of (oxodimethylenemethane)palladium and -platinum complexes in solution and in crystalline states were investigated by H-1 NMR, IR, and X-ray crystallographical analyses. The following features are disclosed: the structures consisted of contributions from pi-allylic and metallacyclobutanone canonical forms; the palladium complex has a larger contribution of pi-allylic character than the platinum complex in both states; the degree of contribution of pi-allylic character increased upon the increment of solvent polarity and the addition of protic solvent.

  DOI：

  10.1021/om00005a060