[Ir(glycine(-1H))(H)(PMe3)3]Cl | 891050-41-2

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: [Ir(glycine(-1H))(H)(PMe3)3]Cl
• CAS: 891050-41-2
• 化学式: C₁₁H₃₂IrNO₂P₃*Cl
• 分子量: 530.975
• InChiKey: FQEZLXGXVFKDMV-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  [Ir(L-alanine(-1H))(H)(PMe3)3]Cl 、 聚甘氨酸 以 水 为溶剂， 生成 [Ir(glycine(-1H))(H)(PMe3)3]Cl
  参考文献：
  名称：

  Iridium(III) hydrido amino acid compounds: Chiral complexes and a helical extended lattice

  摘要：

  [Ir(COD)(PMe3)(3)]Cl, 1, reacts with amino acids in water to yield cationic hydride amino acid complexes, [Ir(aa)(H)(PMe3)(3)]Cl, 2. In general, complexes 2 display octahedral geometry with a meridional arrangement of the PMe3 ligands, with the amino acid chelating through O and N and with hydride trans to N. Disubstituted amino acids on the other hand favor the formation of octahedral complexes with a facial arrangement of PMe3 ligands. The crystal structure of the valine complex, 2c, was obtained and, in addition to confirming the structure of the complex, showed a helical extended lattice structure due to intermolecular N-H-O bonding. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2005.11.028