(E,E)-(12-(hydroxyimino)-13-oxyimino-11,14-diazatetracosane)2Ni | 355137-77-8

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: (E,E)-(12-(hydroxyimino)-13-oxyimino-11,14-diazatetracosane)2Ni
• CAS: 355137-77-8
• 化学式: C₄₄H₉₀N₈NiO₄
• 分子量: 853.94
• InChiKey: SPWNRSFQMRPJER-UHFFFAOYSA-L

反应信息

• 作为反应物：
  描述：

  (E,E)-(12-(hydroxyimino)-13-oxyimino-11,14-diazatetracosane)2Ni 在 氢氧化钾 作用下， 以 甲醇 、 氯仿 为溶剂， 生成 (E,Z)-(12-(hydroxyimino)-13-oxyimino-11,14-diazatetracosane)2Ni
  参考文献：
  名称：

  SYNTHESIS AND COMPLEXATION OF A NEW SOLUBLE MULTIDENTATE DIAMINOGLYOXIME DERIVATIVE

  摘要：

  A new vic-dioxime, 12,13-bis(hydroxyimino)-11,14-diazatetracosane (H2L), has been prepared from decylamine and (E,E)-dichloroglyoxime. Monomeric Ni(II) [(E,E) and (E,Z)], Co(II) and Pd(II) complexes are obtained with a metal-ligand ratio of 1:2. A dimetric complex with UO2 and polymeric Cu(II), Co(II), Pd(II), and (E,Z)-Ni(II) complexes were prepared. All monomeric complexes are very soluble in common organic solvents, but the dimeric uranyl complex and polymeric complexes are not soluble. H-1 and C-13 NMR, IR, MS, and UV-vis data are presented.

  DOI：

  10.1081/sim-100001938
• 作为产物：
  描述：

  (E,Z)-(12-(hydroxyimino)-13-oxyimino-11,14-diazatetracosane)2Ni 在 盐酸 作用下， 以 甲醇 、 氯仿 为溶剂， 生成 (E,E)-(12-(hydroxyimino)-13-oxyimino-11,14-diazatetracosane)2Ni
  参考文献：
  名称：

  SYNTHESIS AND COMPLEXATION OF A NEW SOLUBLE MULTIDENTATE DIAMINOGLYOXIME DERIVATIVE

  摘要：

  A new vic-dioxime, 12,13-bis(hydroxyimino)-11,14-diazatetracosane (H2L), has been prepared from decylamine and (E,E)-dichloroglyoxime. Monomeric Ni(II) [(E,E) and (E,Z)], Co(II) and Pd(II) complexes are obtained with a metal-ligand ratio of 1:2. A dimetric complex with UO2 and polymeric Cu(II), Co(II), Pd(II), and (E,Z)-Ni(II) complexes were prepared. All monomeric complexes are very soluble in common organic solvents, but the dimeric uranyl complex and polymeric complexes are not soluble. H-1 and C-13 NMR, IR, MS, and UV-vis data are presented.

  DOI：

  10.1081/sim-100001938