[Me3Sb(1-phenyl-1H-tetrazole-5-thiol(-1H))2] | 894107-49-4

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 唑类
• 英文名称: [Me3Sb(1-phenyl-1H-tetrazole-5-thiol(-1H))2]
• CAS: 894107-49-4
• 化学式: C₁₇H₁₉N₈S₂Sb
• 分子量: 521.273
• InChiKey: RSLHEFRPYPFKOF-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  三甲基二氯化锑 、 1-苯基-5-巯基四氮唑 在 NaOC₂H₅ 作用下， 以 苯 为溶剂， 以85%的产率得到[Me3Sb(1-phenyl-1H-tetrazole-5-thiol(-1H))2]
  参考文献：
  名称：

  Syntheses, characterizations and crystal structures of new organoantimony(V) complexes with heterocyclic (S,N) ligand

  摘要：

  Eight new organoantimony(V) complexes with 1-phenyl-H-1-tetrazole-5-thiol [(LH)-H-1] and 2,5-dimercapto-4-phenyl-1,3,4-thiodiazole [(LH)-H-2] of the type RnSbL5-n(L=L-1: n=4, R=n-Bu 1, Ph 2, n=3, R=Me 3, Ph 4; L=L-2: n=4, R=n-Bu 5, Ph 6, n=3, R=Me 7, Ph 8) have been synthesized. All the complexes 1-8 have been characterized by elemental, FT-IR, H-1 and C-13 NMR analyses. Among them complexes 2, 6 and 8 have also been confirmed by X-ray crystallography. The structure analyses show that the antimony atoms in complexes 2 and 6 display a trigonal bipyramid geometry, while it displays a distorted capped trigonal prism in complex 8 with two intramolecular Sb...N weak interactions. Furthermore, the supramolecular structure of 2 has been found to consist of one-dimensional linear molecular chain built up by intermolecular C-H...N weak-hydrogen bonds, while a macrocyclic dimer has been found in complex 6 linked by intermolecular C-H...S weak hydrogen bonds with head-to-tail arrangement. Interestingly, one-dimensional helical chain is recognized in complex 8, which is connected by intermolecular C-H...S weak hydrogen bonds. (c) 2006 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2006.01.049