2-(2-hydroxypropyl)-3,5,6-trimethyl-1,4-benzoquinone | 158720-17-3

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 2-(2-hydroxypropyl)-3,5,6-trimethyl-1,4-benzoquinone
• 英文别名: (2-hydroxy-propyl)-trimethyl-[1,4]benzoquinone；(2-Hydroxy-propyl)-trimethyl-[1,4]benzochinon；2-(2-Hydroxypropyl)-3,5,6-trimethylcyclohexa-2,5-diene-1,4-dione
• CAS: 158720-17-3
• 化学式: C₁₂H₁₆O₃
• 分子量: 208.257
• InChiKey: GHHPULWJEUYNCX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.2
• 重原子数：
  15
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  54.4
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  2-(2-hydroxypropyl)-3,5,6-trimethyl-1,4-benzoquinone 、 水 、 alkaline earth salt of/the/ methylsulfuric acid 生成 (+/-)-2.3.5-trimethyl-6-(2-hydroxy-propyl)-hydroquinone
  参考文献：
  名称：

  Effects of phosphate fertilizer levels on cowpea pod-sucking bug populations and damage

  摘要：

  The effect of different application levels of phosphate fertilizer on cowpea pod-sucking bugs [Clavigralla sp., Riptortus sp., Anoplocnemis., Mirperus sp. and Negara sp. (Heteroptera)] was studied using 0 (control), 20, 40 and 60 kg/ha of single super-phosphate. The results showed that the bug densities decreased significantly with increase in rate of application. At 40 and 60 kg/ha, grain yields were significantly higher than at the lower rates of application. Crude protein, fibre, oxalate, phytin, potassium and magnesium contents as well as seed hardness also increased with increase in the rate of fertilizer application.

  DOI：

  10.1080/096708700415544
• 作为产物：
  描述：

  2,3,5-trimethyl-6-prop-2-enylbenzene-1,4-diol 在 甲醇 、 silver(I) acetate 、 吡啶盐酸盐 作用下， 生成 2-(2-hydroxypropyl)-3,5,6-trimethyl-1,4-benzoquinone
  参考文献：
  名称：

  The Chemistry of Vitamin E. XXIII. A New Synthesis of 2,4,6,7-Tetramethyl-5-hydroxycoumaran and of 2-Methyl-5-hydroxycoumaran. Oxidation Products of the Tetramethylcoumaran¹

  摘要：

  DOI：

  10.1021/ja01864a064

文献信息

• Riering, Helmut; Schaefer, Hans J., Chemische Berichte, 1994, vol. 127, # 5, p. 859 - 874
  作者：Riering, Helmut、Schaefer, Hans J.

  DOI：——

  日期：——
• Konstitution und Bestimmung des ?-Tocopherols und einiger �hnlicher Verbindungen
  作者：P. Karrer、R. Escher、H. Fritzsche、H. Keller、B. H. Ringier、H. Salomon

  DOI：10.1002/hlca.193802101124

  日期：——
• Die niedrigeren Homologen des ?-Tocopherols. Oxydationsprodukte tocopherol�hnlicher Verbindungen
  作者：P. Karrer、H. Fritzsche、R. Escher

  DOI：10.1002/hlca.19390220182

  日期：——
• Effects of phosphate fertilizer levels on cowpea pod-sucking bug populations and damage
  作者：Olufemi O. R. Pitan、J. A. Odebiyi、G. O. Adeoye

  DOI：10.1080/096708700415544

  日期：2000.1

  The effect of different application levels of phosphate fertilizer on cowpea pod-sucking bugs [Clavigralla sp., Riptortus sp., Anoplocnemis., Mirperus sp. and Negara sp. (Heteroptera)] was studied using 0 (control), 20, 40 and 60 kg/ha of single super-phosphate. The results showed that the bug densities decreased significantly with increase in rate of application. At 40 and 60 kg/ha, grain yields were significantly higher than at the lower rates of application. Crude protein, fibre, oxalate, phytin, potassium and magnesium contents as well as seed hardness also increased with increase in the rate of fertilizer application.
• The Chemistry of Vitamin E. XXIII. A New Synthesis of 2,4,6,7-Tetramethyl-5-hydroxycoumaran and of 2-Methyl-5-hydroxycoumaran. Oxidation Products of the Tetramethylcoumaran¹
  作者：Lee Irvin Smith、Harvey H. Hoehn、Ambrose G. Whitney

  DOI：10.1021/ja01864a064

  日期：1940.7