[Zn(o-hydroxyacetophenoneglycine(2-))(thiophene-o-carboxaldene-p-toluidine)(H2O)] | 914461-20-4

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: [Zn(o-hydroxyacetophenoneglycine(2-))(thiophene-o-carboxaldene-p-toluidine)(H2O)]
• CAS: 914461-20-4
• 化学式: C₂₂H₂₂N₂O₄SZn
• 分子量: 475.884
• InChiKey: HYYJINSTBGBLQF-PQLVIWEXSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  4-methyl-N-(thiophen-2-ylmethylene)aniline 、 zinc(II) nitrate hexahydrate 、 potassium (N-2-hydroxyacetophenone)glycinate 以 甲醇 、 水 为溶剂， 以56%的产率得到[Zn(o-hydroxyacetophenoneglycine(2-))(thiophene-o-carboxaldene-p-toluidine)(H2O)]
  参考文献：
  名称：

  Synthesis, structural characterization, and antifungal activity of Schiff bases and their transition metal mixed-ligand complexes

  摘要：

  Mixed-ligand complexes of Mn(II), Co(II), Ni(II), Cu(II), Zn(II), and Cd(II) have been prepared with biologically active Schiff bases, viz. potassium salt of o-hydroxyacetophenoneglycine [KHL] and bis(benzylidene)ethylenediamine [A(1)] or thiophene-o-carboxaldene-p-toluidine [A(2)]. The synthesized mixed-ligand complexes have been characterized on the basis of elemental analysis, thermogravimetric analysis, magnetic measurements, and electronic and infrared spectra. The mixed-ligand complexes show higher antifungal activity as compared to the free ligands, metal salts, and the control (dimethylsulfoxide) but moderate activity as compared to the standard fungicides (bavistin and emcarb).

  DOI：

  10.1134/s003602360601013x