Zn(HBTT) | 1394045-40-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 唑类
• 英文名称: Zn(HBTT)
• 英文别名: Zn(1,3,5-tris(2H-tetrazol-5-yl)benzene(-2H))
• CAS: 1394045-40-9
• 化学式: C₉H₄N₁₂*Zn
• 分子量: 345.601
• InChiKey: IECWNFYGLNMSNP-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  1,3,5-tris(2H-tetrazol-5-yl)benzene 、 zinc(II) nitrate hexahydrate 在 HCl 作用下， 以 further solvent(s) 为溶剂， 生成 Zn(HBTT)
  参考文献：
  名称：

  Single-Walled Polytetrazolate Metal–Organic Channels with High Density of Open Nitrogen-Donor Sites and Gas Uptake

  摘要：

  The self-assembly between zinc dimer and 1,3,5-tris(2H-tetrazol-5-yl)benzene (H3BTT), promoted by a urea derivative, leads to a highly porous 3D framework with a large percentage (67%) of N-donor sites unused for bonding with metals. The material exhibits high gas storage capacity (ca. 1.89 wt % H-2 at 77 K and 1 atm; 98 cm(3)/g CO2 at 273 K and I atm), even in the absence of open metal sites. The high percentage of open N-donor sites, coupled with the low framework density resulting from single-walled channels, is believed to contribute to the high uptake capacity.

  DOI：

  10.1021/ja2092882