3,4-di-O-benzyl-1-O-benzyloxymethyl-6-O-t-butyldiphenylsilyl-β-D-fructofuranosyl-(2-1)-(E)-2,3,4-tri-O-benzyl-7,8-dideoxy-10,11:12,13-di-O-isopropylidene-β-L-glycero-D-gluco-D-gluco-tridecadialdo-7-en-1,5-pyranoside | 389885-59-0

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 3,4-di-O-benzyl-1-O-benzyloxymethyl-6-O-t-butyldiphenylsilyl-β-D-fructofuranosyl-(2-1)-(E)-2,3,4-tri-O-benzyl-7,8-dideoxy-10,11:12,13-di-O-isopropylidene-β-L-glycero-D-gluco-D-gluco-tridecadialdo-7-en-1,5-pyranoside
• CAS: 389885-59-0
• 化学式: C₈₄H₉₆O₁₇Si
• 分子量: 1405.76
• InChiKey: FODWCRYXFUHYGH-FSWYEJIUSA-N

反应信息

• 作为反应物：
  描述：

  3,4-di-O-benzyl-1-O-benzyloxymethyl-6-O-t-butyldiphenylsilyl-β-D-fructofuranosyl-(2-1)-(E)-2,3,4-tri-O-benzyl-7,8-dideoxy-10,11:12,13-di-O-isopropylidene-β-L-glycero-D-gluco-D-gluco-tridecadialdo-7-en-1,5-pyranoside 在 臭氧 、 sodium tetrahydroborate 作用下， 以 甲醇 、 二氯甲烷 为溶剂， 以68%的产率得到3,4-di-O-benzyl-1-O-benzyloxymethyl-6-O-t-butyldiphenylsilyl-β-D-fructofuranosyl-(2-1)-(E)-2,3,4-tri-O-benzyl-D-glycero-α-D-glucopyranoside
  参考文献：
  名称：

  REACTION OF SUGAR PHOSPHONATES WITH SUCROSE ALDEHYDES. SYNTHESIS OF HIGHER ANALOGS OF SUCROSE

  摘要：

  The Horner-Emmons reaction between sugar phosphonates Sug-C(O)CH2 P(O)(OMe)(2) and aldehydes derived from sucrose afforded precursors of higher analogs of the general formula Sug-C(O)CH==CH-Suc. An example of the functionalization of the internal three-carbon saccharide connecting unit is provided.

  DOI：

  10.1081/car-100105713
• 作为产物：
  描述：

  3,4-di-O-benzyl-1-O-benzyloxymethyl-6-O-t-butyldiphenylsilyl-β-D-fructofuranosyl-(2-1)-(E)-2,3,4-tri-O-benzyl-7,8-dideoxy-10,11:12,13-di-O-isopropylidene-β-L-galacto-D-gluco-tridecadialdo-7-en-6-ulo-1,5-pyranoside 在 zinc borohydride 作用下， 以 乙醚 为溶剂， 以83%的产率得到3,4-di-O-benzyl-1-O-benzyloxymethyl-6-O-t-butyldiphenylsilyl-β-D-fructofuranosyl-(2-1)-(E)-2,3,4-tri-O-benzyl-7,8-dideoxy-10,11:12,13-di-O-isopropylidene-β-L-glycero-D-gluco-D-gluco-tridecadialdo-7-en-1,5-pyranoside
  参考文献：
  名称：

  REACTION OF SUGAR PHOSPHONATES WITH SUCROSE ALDEHYDES. SYNTHESIS OF HIGHER ANALOGS OF SUCROSE

  摘要：

  The Horner-Emmons reaction between sugar phosphonates Sug-C(O)CH2 P(O)(OMe)(2) and aldehydes derived from sucrose afforded precursors of higher analogs of the general formula Sug-C(O)CH==CH-Suc. An example of the functionalization of the internal three-carbon saccharide connecting unit is provided.

  DOI：

  10.1081/car-100105713