N-(4-Methyl-furazan-3-yl)-N'-(2-methyl-2H-tetrazol-5-yl)-diazene N-oxide | 136853-03-7

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 二嗪类
• 英文名称: N-(4-Methyl-furazan-3-yl)-N'-(2-methyl-2H-tetrazol-5-yl)-diazene N-oxide
• CAS: 136853-03-7
• 化学式: C₅H₆N₈O₂
• 分子量: 210.155
• InChiKey: NOHMRZWTTKIMKC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -0.17
• 重原子数：
  15.0
• 可旋转键数：
  2.0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.4
• 拓扑面积：
  120.95
• 氢给体数：
  0.0
• 氢受体数：
  9.0

反应信息

• 作为产物：
  描述：

  N-(4-Methyl-furazan-3-yl)-N'-(1H-tetrazol-5-yl)-diazene N-oxide 、 硫酸二甲酯 在 sodium carbonate 作用下， 以 丙酮 为溶剂， 反应 40.0h， 以26%的产率得到N-(4-Methyl-furazan-3-yl)-N'-(1-methyl-1H-tetrazol-5-yl)-diazene N-oxide
  参考文献：
  名称：

  Chemical properties of N'-cyanodiazene N-oxides. Reactions involving the nitrile group

  摘要：

  The reactivity of the nitrile group in N'-cyanodiazene N-oxides has been examined for the first time. A general approach to the synthesis of nitrogenous functional derivatives of azoxycarboxylic acids by reaction of N'-cyanodiazene N-oxides with nucleophiles (water, alcohol, and hydroxylamine) is described. A method of synthesis of novel azoxy-1,2,4-oxadiazoles and tetrazoles has been developed in which aliphatic, aromatic, or heterocyclic N'-cyanodiazene N-oxides are reacted with benzonitrile N-oxide or sodium azide. Trimerization of N-cyanodiazene N-oxides, catalyzed by anhydrous HCl, has given novel symm-triazines in which the heterocycle bears three diazene N-oxide groups.

  DOI：

  10.1007/bf00961253