In2Me4(OC(CH3)2CH2OMe)2 | 958336-39-5

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: In2Me4(OC(CH3)2CH2OMe)2
• 英文别名: carbanide;indium(3+);1-methoxy-2-methylpropan-2-olate
• CAS: 958336-39-5
• 化学式: C₁₄H₃₄In₂O₄
• 分子量: 496.062
• InChiKey: WUOAOTNAAWDSJZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.58
• 重原子数：
  20
• 可旋转键数：
  6
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.71
• 拓扑面积：
  64.6
• 氢给体数：
  0
• 氢受体数：
  8

反应信息

• 作为产物：
  描述：

  1-甲氧基-2-甲基-2-丙醇 、 三甲基铟 以 甲苯 为溶剂， 以51%的产率得到In2Me4(OC(CH3)2CH2OMe)2
  参考文献：
  名称：

  Aerosol Assisted Chemical Vapor Deposition of In₂O₃ Films from Me₃In and Donor Functionalized Alcohols

  摘要：

  The reaction of Me(3)ln and ROH (R = CH2CH2NMe2, CH(CH3)CH2NMe2, C(CH3)(2)CH2OMe, CH2CH2OMe) in toluene under aerosol assisted chemical vapor deposition (AACVD) conditions leads to the production of indium oxide thin films on glass. The indium oxide films were deposited at 550 degrees C and analyzed by scanning electron microscopy (SEM), X-ray powder diffraction, wavelength dispersive analysis of X-rays (WDX), X-ray photoelectron spectroscopy (XPS), and Raman spectroscopy. This CVD technique offers a rapid, convenient route to In2O3, which presumably involves the in situ formation of dimethylindium alkoxides, of the type [Me2InOR](2). In order to identify compounds present in the aerosol mist, the solution-phase reaction between Me(3)ln and ROH (R = CH2CH2NMe2, C(CH3)(2)CH2OMe, CH(CH3)CH2NMe2, CH(CH2NMe2)(2)) at room temperature in toluene was carried out. Dimeric indium alkoxides, of the type [Me2In(OR)](2), were isolated, and their structures were determined by X-ray crystallography.

  DOI：

  10.1021/ic701372b