9-(aminomethyl)phenanthrene | 166898-48-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 菲及其衍生物
• 英文名称: 9-(aminomethyl)phenanthrene
• 英文别名: Phenanthren-2-ylmethanamine
• CAS: 166898-48-2
• 化学式: C₁₅H₁₃N
• 分子量: 207.275
• InChiKey: OSWSQZCAWIDDFO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.6
• 重原子数：
  16
• 可旋转键数：
  1
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.07
• 拓扑面积：
  26
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  9-(aminomethyl)phenanthrene 在 potassium carbonate 、 三乙胺 作用下， 以 甲醇 、 二氯甲烷 为溶剂， 反应 0.33h， 生成 <<1⁵,3⁵,5⁵,7⁵-tetra-teet-butyl-7²-<<<(9-phennathrene)methyl>carbamoyl>methoxy>-1,3,5,7-tetrabenzocyclooctophane-1²,3²,5²-triyl>trioxy>triacetic acid
  参考文献：
  名称：

  New Sensitizer-Modified Calix[4]arenes Enabling Near-UV Excitation of Complexed Luminescent Lanthanide Ions

  摘要：

  The synthesis is described of a series of calix[4]arenes with three different sensitizer chromophores (''antenna'') attached to the lower rim via a short spacer. In the Eu3+ and Tb3+ complexes of these calixarenes, photoexcitation of the antenna can induce lanthanide emission via intramolecular energy transfer. Although the higher energy of the Tb3+ luminescent state makes it more difficult to sensitize than in the case of Eu3+, especially a triphenylene antenna is found to have strong sensitizing ability toward not only Eu3+ but also Tb3+, allowing excitation of the lanthanide with wavelengths extending to 350 nm.

  DOI：

  10.1021/ja00142a004
• 作为产物：
  描述：

  菲-2-腈 在 diborane(6) 作用下， 以 四氢呋喃 为溶剂， 反应 2.0h， 以73%的产率得到9-(aminomethyl)phenanthrene
  参考文献：
  名称：

  New Sensitizer-Modified Calix[4]arenes Enabling Near-UV Excitation of Complexed Luminescent Lanthanide Ions

  摘要：

  The synthesis is described of a series of calix[4]arenes with three different sensitizer chromophores (''antenna'') attached to the lower rim via a short spacer. In the Eu3+ and Tb3+ complexes of these calixarenes, photoexcitation of the antenna can induce lanthanide emission via intramolecular energy transfer. Although the higher energy of the Tb3+ luminescent state makes it more difficult to sensitize than in the case of Eu3+, especially a triphenylene antenna is found to have strong sensitizing ability toward not only Eu3+ but also Tb3+, allowing excitation of the lanthanide with wavelengths extending to 350 nm.

  DOI：

  10.1021/ja00142a004

文献信息

• [EN] COMPOUND, ORGANIC ELECTROLUMINESCENT ELEMENT MATERIAL, ORGANIC ELECTROLUMINESCENT ELEMENT, AND ELECTRONIC DEVICE<br/>[FR] COMPOSÉ, MATÉRIAU D'ÉLÉMENT ÉLECTROLUMINESCENT ORGANIQUE, ÉLÉMENT ÉLECTROLUMINESCENT ORGANIQUE ET DISPOSITIF ÉLECTRONIQUE<br/>[JA] 化合物、有機エレクトロルミネッセンス素子用材料、有機エレクトロルミネッセンス素子、及び電子機器
  申请人：[en]IDEMITSU KOSAN CO.,LTD.;[ja]出光興産株式会社

  公开号：WO2022264827A1

  公开（公告）日：2022-12-22

  下記式（１）で表される化合物。