| 1429808-21-8

• 分子结构分类: 有机化合物 - 有机氧化合物
• CAS: 1429808-21-8
• 化学式: C₆H₁₁O₃
• 分子量: 131.152
• InChiKey: BFCKAPGFZNYFTB-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  丙酮缩甘油 在 iron(III) chloride 作用下， 反应 0.67h， 生成
  参考文献：
  名称：

  Antiradical activity of dioxolane derivatives

  摘要：

  1,3-Benzodioxoles synthesized by condensation of 3,6-di-tert-butylbenzene-1,2-diol with carbonyl compounds showed antiradical activity due to their ability to undergo one-electron oxidation with formation of stable radical cations. On this basis, the antiknock effect of their structural analogs, 1,3-dioxolanes derived from vicinal diols, was interpreted in terms of oxidation of these compounds with active radicals generated from fuel hydrocarbons to produce more stable radical or radical ion species, depending on the fuel composition. The formation of radical species was detected in model oxidation reactions of 2,2-dimethyl-1,3-dioxolane and 2,2-dimethyl-1,3-dioxolan-4-ylmethanol with radicals generated by photolysis of iron(III) chloride and benzoyl peroxide.

  DOI：

  10.1134/s1070428013030226