(Ph3P)2Pt[η(2)-CH3CC.tplbond.CC.tplbond.CCH3] | 34700-10-2

• 英文名称: (Ph3P)2Pt[η(2)-CH3CC.tplbond.CC.tplbond.CCH3]
• CAS: 34700-10-2
• 化学式: C₄₂H₃₆P₂Pt
• 分子量: 797.775
• InChiKey: KUTOOYIWBOIEJS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  (Ph3P)2Pt[η(2)-CH3CC.tplbond.CC.tplbond.CCH3] 、 三氟乙酸 以 二氯甲烷-D2 为溶剂， 生成 trans-(Ph3P)2(CF3CO2)Pt[η(1)-(E-CH3CH=)CC.tplbond.CCH3]
  参考文献：
  名称：

  Formation of platinum allyl and propargyl complexes from protonation of platinum enyne and diyne complexes

  摘要：

  Protonation of (Ph3P)(2)Pt[eta(2)-HC drop CC(CH3)=CH2] (2a) with excess HBF4 . Et2O produced the pi-allyl complex (Ph3P)(2)Pt[eta(3)- H2C=CC(CH3)=CH2]+BF4-(3a-BF4) instead of a pi-propargyl complex. Reaction of excess CF3CO2H with 2a initially produced the analogous pi-allyl complex 3a-CF3CO2 which then added CF3CO2H across the vinylidene unit of 3a-CF3CO2 to give the pi-allyl complex (Ph3P)(2)Pt[eta(3)-CH3C(CF3CO2) C(CH3)CH2]+CF3CO2-(5a). Protonation of the platinum diyne complex [(p-CH3-C6H4)(3)P](2)Pt(eta(2)- CH3C drop CC drop CCH3) (7b) with HBF4Et2O at -73 degrees C initially produced the platinum hydride complex trans-[(p-CH3-C6H4)(3)P](2)- PtH(eta(2)-CH3C drop CC drop CCH3)+BF4-(9), which rearranged to the platinum pi-propargyl complex [(p-CH3-C6H4)(3)P](2)Pt[eta(3)-(CH3CH=)-CC drop CCH3]+BF4-(11) at -28 degrees C. (C) 1997 Elsevier Science S.A.

  DOI：

  10.1016/s0020-1693(97)05640-5
• 作为产物：
  描述：

  乙烯双(三苯基磷)铂 、 2,4-己二炔 以 四氢呋喃 为溶剂， 以41%的产率得到(Ph3P)2Pt[η(2)-CH3CC.tplbond.CC.tplbond.CCH3]
  参考文献：
  名称：

  Formation of platinum allyl and propargyl complexes from protonation of platinum enyne and diyne complexes

  摘要：

  Protonation of (Ph3P)(2)Pt[eta(2)-HC drop CC(CH3)=CH2] (2a) with excess HBF4 . Et2O produced the pi-allyl complex (Ph3P)(2)Pt[eta(3)- H2C=CC(CH3)=CH2]+BF4-(3a-BF4) instead of a pi-propargyl complex. Reaction of excess CF3CO2H with 2a initially produced the analogous pi-allyl complex 3a-CF3CO2 which then added CF3CO2H across the vinylidene unit of 3a-CF3CO2 to give the pi-allyl complex (Ph3P)(2)Pt[eta(3)-CH3C(CF3CO2) C(CH3)CH2]+CF3CO2-(5a). Protonation of the platinum diyne complex [(p-CH3-C6H4)(3)P](2)Pt(eta(2)- CH3C drop CC drop CCH3) (7b) with HBF4Et2O at -73 degrees C initially produced the platinum hydride complex trans-[(p-CH3-C6H4)(3)P](2)- PtH(eta(2)-CH3C drop CC drop CCH3)+BF4-(9), which rearranged to the platinum pi-propargyl complex [(p-CH3-C6H4)(3)P](2)Pt[eta(3)-(CH3CH=)-CC drop CCH3]+BF4-(11) at -28 degrees C. (C) 1997 Elsevier Science S.A.

  DOI：

  10.1016/s0020-1693(97)05640-5