(2,3,7,8,12,13,17,18-octakis[3,5-bis(trifluoromethyl)phenyl]-2-seco-2,3-dioxoporphyrazinato)cobalt(II) | 1290041-24-5

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: (2,3,7,8,12,13,17,18-octakis[3,5-bis(trifluoromethyl)phenyl]-2-seco-2,3-dioxoporphyrazinato)cobalt(II)
• CAS: 1290041-24-5
• 化学式: C₈₀H₂₄CoF₄₈N₈O₂
• 分子量: 2100.04
• InChiKey: CACSPQIXSURFHT-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  2,3,7,8,12,13,17,18-octakis[3,5-bis(trifluoromethyl)phenyl]-2-seco-porphyrazine-2,3-dione 在 cobalt(II) acetate 作用下， 以 乙醇 、 氯仿 为溶剂， 反应 4.0h， 以74%的产率得到(2,3,7,8,12,13,17,18-octakis[3,5-bis(trifluoromethyl)phenyl]-2-seco-2,3-dioxoporphyrazinato)cobalt(II)
  参考文献：
  名称：

  Synthesis and characterization of new soluble fluorinated seco-porphyrazines

  摘要：

  Magnesium porphyrazinate substituted with eight 3,5-bis(trifluoromethyl)phenyl groups on the peripheral positions has been synthesized by the cyclotetramerization of 3,4[3,5-bis(trifluoromethyl)-phenyl]pyrroline-2,5-diimine in the presence of magnesium butanolate. Acid-mediated demetallation of the magnesium porphyrazine resulted in peripheral oxidation of one pyrrole ring to reveal the seco-porphyrazine, octakis[3,5-bis(trifluoromethyl)phenyl]-2-seco-porphyrazine-2,3-dione. Further reaction of this product with copper (II) acetate, zinc (II) acetate and cobalt (II) acetate has led to the metallo-derivatives, {octakis[3,5-bis(trifluoromethyl)phenyl]-2-seco-2,3-dioxoporphyrazinato} M(II) [M = Cu(II), Zn(II), Co(II)]. These new soluble complexes were characterized by elemental analysis, together with FT-IR, H-1 NMR, C-13 NMR, F-19 NMR, UV-Vis and mass spectral data. (C) 2011 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2011.01.003