2-octanoyl-1,3-cyclopentanedion | 126985-11-3

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 2-octanoyl-1,3-cyclopentanedion
• 英文别名: 2-nonanoylcyclopentane-1,3-dione
• CAS: 126985-11-3
• 化学式: C₁₄H₂₂O₃
• 分子量: 238.327
• InChiKey: NEUUADXATUOIEX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.1
• 重原子数：
  17
• 可旋转键数：
  8
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.79
• 拓扑面积：
  51.2
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  2-octanoyl-1,3-cyclopentanedion 生成 3-chloro-2-nonanoylcyclopent-2-en-1-one
  参考文献：
  名称：

  LAXVICH, F. A.;XLEBNIKOVA, T. S., VESTSI AN BSSR. CEP. XIM. N.,(1989) N, S. 39-45

  摘要：

  DOI：

文献信息

• Platinum(II) cationic complexes with derivatives of 2-acyl-1,3-cyclopentanedions
  作者：T. S. Khlebnikova、I. V. Merkushin、F. A. Lakhvich

  DOI：10.1134/s107036320605001x

  日期：2006.5

  cis-Diammineplatinum(II) complexes containing 2-acyl-1,3-cyclopentadion fragments as a bidentate acido ligand were prepared by the transformation of cis-diamminediiodoplatinum(II) to cis-diamminesulfatoplatinum(II) under the action of silver sulfate with the subsequent treatment of the resulting complex by barium hydroxide and by the reaction of the synthesized base with a twofold amount of 2-acyl-1,3-cyclopentanedion. The products are the cationic complexes of cis-diammineplatinum(II) and contain 2-acyl-1,3-cyclopentanedionate as a bidentate acido ligand, which chelates platinum atom by the carbonyl groups of side acyl chain and one group connected with five-membered cycle, whereas a 2-acyl-1,3-cyclopentadion enolate anion forms counter ion.