4-[[3-(2,6,7-trioxabicyclo[2.2.2]octan-4-ylmethoxy)-2-[[3-[3-(2,6,7-trioxabicyclo[2.2.2]octan-4-ylmethoxy)-2,2-bis(2,6,7-trioxabicyclo[2.2.2]octan-4-ylmethoxymethyl)propoxy]-2,2-bis[[3-(2,6,7-trioxabicyclo[2.2.2]octan-4-ylmethoxy)-2,2-bis(2,6,7-trioxabicyclo[2.2.2]octan-4-ylmethoxymethyl)propoxy]methyl]propoxy]methyl]-2-(2,6,7-trioxabicyclo[2.2.2]octan-4-ylmethoxymethyl)propoxy]methyl]-2,6,7-trioxabicyclo[2.2.2]octane | 110637-31-5

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 4-[[3-(2,6,7-trioxabicyclo[2.2.2]octan-4-ylmethoxy)-2-[[3-[3-(2,6,7-trioxabicyclo[2.2.2]octan-4-ylmethoxy)-2,2-bis(2,6,7-trioxabicyclo[2.2.2]octan-4-ylmethoxymethyl)propoxy]-2,2-bis[[3-(2,6,7-trioxabicyclo[2.2.2]octan-4-ylmethoxy)-2,2-bis(2,6,7-trioxabicyclo[2.2.2]octan-4-ylmethoxymethyl)propoxy]methyl]propoxy]methyl]-2-(2,6,7-trioxabicyclo[2.2.2]octan-4-ylmethoxymethyl)propoxy]methyl]-2,6,7-trioxabicyclo[2.2.2]octane
• CAS: 110637-31-5
• 化学式: C₉₇H₁₄₈O₅₂
• 分子量: 2146.21
• InChiKey: AMGJFWTXAHNBEK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -1.65
• 重原子数：
  149.0
• 可旋转键数：
  64.0
• 环数：
  36.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  479.96
• 氢给体数：
  0.0
• 氢受体数：
  52.0

反应信息

• 作为反应物：
  描述：

  4-[[3-(2,6,7-trioxabicyclo[2.2.2]octan-4-ylmethoxy)-2-[[3-[3-(2,6,7-trioxabicyclo[2.2.2]octan-4-ylmethoxy)-2,2-bis(2,6,7-trioxabicyclo[2.2.2]octan-4-ylmethoxymethyl)propoxy]-2,2-bis[[3-(2,6,7-trioxabicyclo[2.2.2]octan-4-ylmethoxy)-2,2-bis(2,6,7-trioxabicyclo[2.2.2]octan-4-ylmethoxymethyl)propoxy]methyl]propoxy]methyl]-2-(2,6,7-trioxabicyclo[2.2.2]octan-4-ylmethoxymethyl)propoxy]methyl]-2,6,7-trioxabicyclo[2.2.2]octane 在 盐酸 作用下， 以 甲醇 为溶剂， 反应 3.0h， 生成 2-[[3-[3-Hydroxy-2,2-bis(hydroxymethyl)propoxy]-2-[[3-[3-[3-hydroxy-2,2-bis(hydroxymethyl)propoxy]-2,2-bis[[3-hydroxy-2,2-bis(hydroxymethyl)propoxy]methyl]propoxy]-2,2-bis[[3-[3-hydroxy-2,2-bis(hydroxymethyl)propoxy]-2,2-bis[[3-hydroxy-2,2-bis(hydroxymethyl)propoxy]methyl]propoxy]methyl]propoxy]methyl]-2-[[3-hydroxy-2,2-bis(hydroxymethyl)propoxy]methyl]propoxy]methyl]-2-(hydroxymethyl)propane-1,3-diol
  参考文献：
  名称：

  Starburst polyether dendrimers

  摘要：

  DOI：

  10.1021/jo00233a002
• 作为产物：
  描述：

  3,5,8-三氧杂双环[2.2.2]辛烷-1-甲醇 、 1,3-bis[3-bromo-2,2-bis(bromomethyl)propoxy]-2,2-bis[[3-bromo-2,2-bis(bromomethyl)propoxy]methyl]propane 在 potassium hydride 作用下， 生成 4-[[3-(2,6,7-trioxabicyclo[2.2.2]octan-4-ylmethoxy)-2-[[3-[3-(2,6,7-trioxabicyclo[2.2.2]octan-4-ylmethoxy)-2,2-bis(2,6,7-trioxabicyclo[2.2.2]octan-4-ylmethoxymethyl)propoxy]-2,2-bis[[3-(2,6,7-trioxabicyclo[2.2.2]octan-4-ylmethoxy)-2,2-bis(2,6,7-trioxabicyclo[2.2.2]octan-4-ylmethoxymethyl)propoxy]methyl]propoxy]methyl]-2-(2,6,7-trioxabicyclo[2.2.2]octan-4-ylmethoxymethyl)propoxy]methyl]-2,6,7-trioxabicyclo[2.2.2]octane
  参考文献：
  名称：

  Starburst polyether dendrimers

  摘要：

  DOI：

  10.1021/jo00233a002

文献信息

• PADIAS, ANNE BUYLE;HALL, H. K., JR.;TOMALIA, DONALD A.;MCCONNELL, J. R., J. ORG. CHEM., 52,(1987) N 24, 5305-5312
  作者：PADIAS, ANNE BUYLE、HALL, H. K., JR.、TOMALIA, DONALD A.、MCCONNELL, J. R.

  DOI：——

  日期：——