(E)-2-((2S,3S)-2-tert-Butoxycarbonylamino-3-methyl-pentanoylamino)-3-(toluene-4-sulfonyloxy)-acrylic acid methyl ester | 855738-96-4

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: (E)-2-((2S,3S)-2-tert-Butoxycarbonylamino-3-methyl-pentanoylamino)-3-(toluene-4-sulfonyloxy)-acrylic acid methyl ester
• CAS: 855738-96-4
• 化学式: C₂₂H₃₂N₂O₈S
• 分子量: 484.571
• InChiKey: UHOMOZJJSOMRTA-YJBOKZPZSA-N

反应信息

• 作为反应物：
  描述：

  (E)-2-((2S,3S)-2-tert-Butoxycarbonylamino-3-methyl-pentanoylamino)-3-(toluene-4-sulfonyloxy)-acrylic acid methyl ester 在 三乙胺 、 三氟乙酸 作用下， 以 甲醇 、 二氯甲烷 为溶剂， 反应 2.0h， 生成 Toluene-4-sulfonic acid (S)-5-((S)-sec-butyl)-3,6-dioxo-piperazin-(2Z)-ylidenemethyl ester
  参考文献：
  名称：

  Synthesis of Cyclic Endiamino Peptides

  摘要：

  Several building blocks for endiamino peptides, as well as several cyclic endiamino peptides themselves, and pyrazin-6-one, which embodies the endiamino group, were prepared. The variety of synthesized compounds shows the potential of this synthesis in the preparation of many different groups of compounds.

  DOI：

  10.1021/ja050299r
• 作为产物：
  描述：

  Boc-L-Ile-D,L-Ser-OMe 、 对甲苯磺酰氯 在 二甲基亚砜 、 三乙胺 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 生成 (E)-2-((2S,3S)-2-tert-Butoxycarbonylamino-3-methyl-pentanoylamino)-3-(toluene-4-sulfonyloxy)-acrylic acid methyl ester
  参考文献：
  名称：

  Synthesis of Cyclic Endiamino Peptides

  摘要：

  Several building blocks for endiamino peptides, as well as several cyclic endiamino peptides themselves, and pyrazin-6-one, which embodies the endiamino group, were prepared. The variety of synthesized compounds shows the potential of this synthesis in the preparation of many different groups of compounds.

  DOI：

  10.1021/ja050299r