Te-1-methylphenacyl 1-methylethanecarbotelluroate | 1236132-46-9

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: Te-1-methylphenacyl 1-methylethanecarbotelluroate
• CAS: 1236132-46-9
• 化学式: C₁₃H₁₆O₂Te
• 分子量: 331.869
• InChiKey: GLPZLMWGVIESEH-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  Te-1-methylphenacyl 1-methylethanecarbotelluroate 反应 5.0h， 生成 (E)-1-phenyl-1-methylethenyl 2-methylpropanoate 、 (Z)-1-phenyl-1-methylethenyl 2-methylpropanoate
  参考文献：
  名称：

  Te-1-Acylmethyl and Te-1-Iminoalkyl Telluroesters: Synthesis and Thermolysis Leading to 1,3-Diketones and O-Alkenyl and O-Imino Esters

  摘要：

  A series of Te-1-acylmethyl carbotelluroates was prepared in good isolated yields from the reaction of potassium carbotelluroates with -haloketones in acetonitrile. Thermolysis of the telluroesters afforded vinyl esters in 20-50% yields, while treatment of the carbotellurorates with potassium t-butanolate led to 1,3-diketones in 30-75% yields with the liberation of black tellurium. The reaction of potassium carbotelluroates with -haloaceto oximes gave O-acyl oximes in 50-70% yields via Te-1-iminomethylcarbotelluroates.

  DOI：

  10.1080/10426501003769728