| 1224514-71-9

• 分子结构分类: 有机化合物 - 有机氧化合物
• CAS: 1224514-71-9
• 化学式: C₁₄H₂₅NO₅
• 分子量: 287.356
• InChiKey: GVRJVYRUARAGPS-VHSXEESVSA-N

反应信息

• 作为产物：
  描述：

  (4S)-4-(tert-butoxycarbonylamino)pent-1-en-3-yl pivalate 在 臭氧 作用下， 生成 、
  参考文献：
  名称：

  An enantioselective synthesis of the bicyclic core of the marine natural product awajanomycin

  摘要：

  A concise stereoselective synthesis of the N-benzylated bicyclic core of the marine natural product awajanomycin is described starting with naturally Occurring L-alanine. Key steps in the synthesis include a ring-closing metathesis to establish a delta-lactam ring followed by a stereoselective hydroxylation to instal the quaternary centre. (C) 2010 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2010.01.123