[(H2O)(acetamidato)Pt(μ-acetamidato)2Pt(acetamidato)(H2O)] | 67275-90-5

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: [(H2O)(acetamidato)Pt(μ-acetamidato)2Pt(acetamidato)(H2O)]
• CAS: 67275-90-5
• 化学式: C₈H₂₀N₄O₆Pt₂
• 分子量: 658.43
• InChiKey: ABWBFQHPAMTVGU-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [(H2O)(acetamidato)Pt(μ-acetamidato)2Pt(acetamidato)(H2O)] 以 neat (no solvent) 为溶剂， 生成 铂
  参考文献：
  名称：

  Thermolysis of polynuclear platinum(II) acetamidato complexes

  摘要：

  The thermolysis of five polynuclear Pt(II) acetamidato complexes with known structures (I-V) and platinum blue of the composition Pt(NHCOCH3)(2) center dot H2O prepared by two different procedures (VI and VIa) has been studied by differential scanning calorimetry and thermogravimetry. The results of studying the thermolysis of these complexes allows one to assume that the structures of VI and VIa are different: complex VI is polynuclear and consists of binuclear fragments[(H2O)(NHCOCH3)Pt(mu-NHCOCH3)(2)Pt(NHCOCH3)(H2O)], whereas complex VIa is built of fragments [(H2O)(NHCOCH3)Pt(mu-OH)(mu-OH)(mu-NHCOCH3)Pt(NHCOCH3)(2)].

  DOI：

  10.1134/s0036023607060149
• 作为产物：
  描述：

  乙酰胺 、 potassium tetrachloroplatinate(II) 、 水 以 水 为溶剂， 以15%的产率得到[(H2O)(acetamidato)Pt(μ-acetamidato)2Pt(acetamidato)(H2O)]
  参考文献：
  名称：

  Thermolysis of polynuclear platinum(II) acetamidato complexes

  摘要：

  The thermolysis of five polynuclear Pt(II) acetamidato complexes with known structures (I-V) and platinum blue of the composition Pt(NHCOCH3)(2) center dot H2O prepared by two different procedures (VI and VIa) has been studied by differential scanning calorimetry and thermogravimetry. The results of studying the thermolysis of these complexes allows one to assume that the structures of VI and VIa are different: complex VI is polynuclear and consists of binuclear fragments[(H2O)(NHCOCH3)Pt(mu-NHCOCH3)(2)Pt(NHCOCH3)(H2O)], whereas complex VIa is built of fragments [(H2O)(NHCOCH3)Pt(mu-OH)(mu-OH)(mu-NHCOCH3)Pt(NHCOCH3)(2)].

  DOI：

  10.1134/s0036023607060149