4-((2Z)-6,6-diethoxy-hex-2-enyl)-1,5,5-trimethyl-cyclopentene | 1031729-23-3

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 4-((2Z)-6,6-diethoxy-hex-2-enyl)-1,5,5-trimethyl-cyclopentene
• 英文别名: (Z)-4-(6,6-diethoxy-hex-2-enyl)-1,5,5-trimethyl-cyclopentene；4-[(Z)-6,6-diethoxyhex-2-enyl]-1,5,5-trimethylcyclopentene
• CAS: 1031729-23-3
• 化学式: C₁₈H₃₂O₂
• 分子量: 280.451
• InChiKey: SXXDYTDAQLGNHE-HJWRWDBZSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.6
• 重原子数：
  20
• 可旋转键数：
  9
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.78
• 拓扑面积：
  18.5
• 氢给体数：
  0
• 氢受体数：
  2

文献信息

• Use of campholenic derivatives as fragrant ingredients in perfumery and flavouring
  申请人：V. Mane Fils

  公开号：EP1930317A1

  公开（公告）日：2008-06-11

  This invention relates to campholenic derivatives of general formula (I) Wherein R1, R2, R3, R4 and R5 represent, each independently, a hydrogen atom or a linear or branched C1-C5 alkyl or C1-C5 alkenyl group, Y represents a CN, a C(O)R6 or a CR6 (ORα) (ORβ) group, wherein R6 represents a hydrogen atom or a linear or branched C1-C5 alkyl or C1-C5 alkenyl group, and Rα and Rβ represent simultaneously a linear or branched C1, C2, C3, C4 or C5 alkyl or alkenyl group and can form together a cycle, the 5-membered ring is saturated or has a double bond between C3' and C4' in formula (I), and the side chain, optionally, has a double bond between C1 and C2 and/or between C3 and C4, provided that the derivative is not 3-methyl-6-(2,2,3-trimethyl-cyclopent-3-enyl)-hex-4-enal; and their use as fragrant or flavouring agent.

  本发明涉及一般式（I）的萜烯衍生物，其中R1、R2、R3、R4和R5分别表示氢原子或线性或支链C1-C5烷基或C1-C5烯基基团，Y表示CN、C（O）R6或CR6（ORα）（ORβ）基团，其中R6表示氢原子或线性或支链C1-C5烷基或C1-C5烯基基团，而Rα和Rβ同时表示线性或支链C1、C2、C3、C4或C5烷基或烯基基团，并可形成一个环，5-成员环在公式（I）中是饱和的或在C3'和C4'之间具有双键，侧链可选地在C1和C2之间和/或在C3和C4之间具有双键，前提是该衍生物不是3-甲基-6-（2,2,3-三甲基环戊-3-烯基）-己-4-烯醛；以及它们作为香料或调味剂的用途。
• USE OF NEW CAMPHOLENIC DERIVATIVES AS FRAGRANT INGREDIENTS IN PERFUMERY AND FLAVOURING
  申请人：Mane Jean

  公开号：US20080138482A1

  公开（公告）日：2008-06-12

  This invention relates to campholenic derivatives of general formula (I) Wherein R1, R2, R3, R4 and R5 represent, each independently, a hydrogen atom or a linear or branched C 1 -C 5 alkyl or C 2 -C 5 alkenyl group, Y represents a CN, a C(O)R 6 or a CR 6 (OR α ) (OR β ) group, wherein R 6 represents a hydrogen atom or a linear or branched C 1 -C 5 alkyl or C 2 -C 5 alkenyl group, and R α and R β represent simultaneously a linear or branched C 1 , C 2 , C 3 , C 4 or C 5 alkyl or C 2 , C 3 , C 4 or C 5 alkenyl group and can form together a cycle, the 5-membered ring is saturated or has a double bond between C3′ and C4′ in formula (I), and the side chain, optionally, has a double bond between C1 and C2 and/or between C3 and C4, provided that the derivative is not 3-methyl-6-(2,2,3-trimethyl-cyclopent-3-enyl)-hex-4-enal; and their use as fragrant or flavouring agent.

  本发明涉及通式（I）的香松烯衍生物，其中R1、R2、R3、R4和R5分别表示氢原子或线性或支链C1-C5烷基或C2-C5烯基基团，Y表示CN、C（O）R6或CR6（ORα）（ORβ）基团，其中R6表示氢原子或线性或支链C1-C5烷基或C2-C5烯基基团，而Rα和Rβ同时表示线性或支链C1、C2、C3、C4或C5烷基或C2、C3、C4或C5烯基基团，并且可以一起形成一个环，式（I）中的5-成员环是饱和的或在C3'和C4'之间具有双键，而侧链可选择在C1和C2之间和/或在C3和C4之间具有双键，前提是该衍生物不是3-甲基-6-（2,2,3-三甲基-环戊-3-烯基）-己-4-烯醛；以及它们作为香料或调味剂的用途。
• USE OF CAMPHOLENIC DERIVATIVES AS FRAGRANT INGREDIENTS IN PERFUMERY AND FLAVOURING
  申请人：V. Mane Fils

  公开号：EP2094650A1

  公开（公告）日：2009-09-02
• [EN] USE OF CAMPHOLENIC DERIVATIVES AS FRAGRANT INGREDIENTS IN PERFUMERY AND FLAVOURING<br/>[FR] UTILISATION DE DÉRIVÉS CAMPHOLÉNIQUES COMME INGRÉDIENTS PARFUMANTS EN PARFUMERIE ET EN AROMATISATION
  申请人：MANE FILS V

  公开号：WO2008068310A1

  公开（公告）日：2008-06-12

  [EN] This invention relates to campholenic derivatives of general formula (I) wherein Rl, R2, R3, R4 and R5 represent, each independently, a hydrogen atom or a linear or branched C₁-C₅ alkyl or C₂-C₅ alkenyl group, Y represents a CN, a C(O)R₆ or a CR₆ (ORa) (ORß) group, wherein R₆ represents a hydrogen atom or a linear or branched C₁-C₅ alkyl or C₂-C₅ alkenyl group, and Ra and Rß represent simultaneously a linear or branched C₁, C₂, C₃, C₄ or C₅ alkyl or C₂, C₃, C₄ or C₅ alkenyl group and can form together a cycle, the 5-membered ring is saturated or has a double bond between C3 ' and C4 ' in formula (I), and the side chain, optionally, has a double bond between C1 and C2 and/or between C3 and C4, provided that the derivative is not 3-methyl-6- (2, 2, 3-trimethyl-cyclopent-3-enyl) -hex-4-enal; and their use as fragrant or flavouring agent.
  [FR] La présente invention concerne des dérivés campholéniques de formule générale (I), dans laquelle Rl, R2, R3, R4 et R5 représentent, chacun indépendamment, un atome d'hydrogène ou un groupe alkyle C₁-C₅ ou alcényle C₂-C₅ linéaire ou ramifié; Y représente un groupe CN, C(O)R₆ ou CR₆ (ORa) (ORß), où R₆ représente un atome d'hydrogène ou un groupe alkyle C₁-C₅ ou alcényle C₂-C₅ linéaire ou ramifié, et Ra et Rß représentent simultanément un groupe alkyle C₁, C₂, C₃, C₄ ou C₅ ou alcényle C₁, C₂, C₃, C₄ ou C₅ linéaire ou ramifié et peuvent ensemble former un cycle, le noyau à cinq chaînons est saturé ou présente une liaison double entre C3 ' et C4 ' dans la formule (I), et la chaîne latérale, éventuellement, présente une liaison double entre C1 et C2 et/ou entre C3 et C4, à condition que le dérivé ne soit pas 3-méthyl-6- (2, 2, 3-triméthyl-cyclopent-3-ényl) -hex-4-enal. L'invention concerne également l'utilisation des dérivés en tant qu'agent parfumant ou aromatisant.