copper tetra-4-(3,4-dimethylphenoxy)-5-(4-nitrophenoxy)phthalocyanine | 512179-15-6

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: copper tetra-4-(3,4-dimethylphenoxy)-5-(4-nitrophenoxy)phthalocyanine
• CAS: 512179-15-6
• 化学式: C₈₈H₆₀CuN₁₂O₁₆
• 分子量: 1605.06
• InChiKey: IUKUQXASQIFRJL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  copper diacetate 、 4-(3,4-dimethylphenoxy)-5-(4-nitrophenoxy)phthalodinitrile 以 氯仿 为溶剂， 以40%的产率得到copper tetra-4-(3,4-dimethylphenoxy)-5-(4-nitrophenoxy)phthalocyanine
  参考文献：
  名称：

  摘要：

  4-(3,4-Dimethylphenoxy)-5-(4-nitrophenoxy)phthalodinitrile was prepared by stepwise nucleophilic substitution of bromine and then the nitro group in 4-bromo-5-nitrophthalodinitrile by the substituted phenoxy groups and was converted to the corresponding octasubstituted copper phthalocyanine by the reaction with copper acetate. The spectroscopic and mesomorphic properties of the resulting complex were studied. It exhibits thermotropic mesomorphism and forms an M phase in the range 85-155degreesC.

  DOI：

  10.1023/a:1021698417760