[Hg(benzilbisthiosemicarbazone)(NO3)2] | 392233-16-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 唑类
• 英文名称: [Hg(benzilbisthiosemicarbazone)(NO3)2]
• CAS: 392233-16-8
• 化学式: C₁₆H₁₆HgN₈O₆S₂
• 分子量: 681.075
• InChiKey: JTNAQVYLKPOGQT-SKTPHEQHSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  mercuric(II) nitrate monohydrate 、 benzil bis(thiosemicarbazone) 以 乙醇 为溶剂， 以42%的产率得到[Hg(benzilbisthiosemicarbazone)(NO3)2]
  参考文献：
  名称：

  Synthesis and characterisation of zinc, cadmium and mercury complexes of benzilbisthiosemicarbazone. Structure of cadmium derivative

  摘要：

  Complexes [MLH6(NO3)(2)] (M = Cd, Hg) (1 and 2), [MLH4] (M = Hg, Zn) (3 and 5) and [ZnLH5NO3] (4) have been synthesised by reaction of benzilbisthiosemicarbazone LH6 with cadmium, mercury and zinc nitrates in ethanol. The X-ray diffraction study of cadmium complex 1 shows that the azomethine nitrogen atoms, the sulfur atoms and the nitrate groups are bonded to the cadmium atom giving, the first time for this kind of ligands, a distorted octahedral geometry. Complexes have been characterised by elemental analyses and mass spectra as well as by IR, H-1, C-13 and Cd-113 NMR and C-13 and Cd-113 CP/MAS NMR spectroscopies. In all complexes LH6 acts as a tetradentate N2S2 ligand. The electrochemical behaviour of complexes, studied by cyclic voltammetry, shows metal centred and ligand reduction processes for all of them. (C) 2001 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0020-1693(01)00607-7