mercuric(II) nitrate monohydrate

• 分子结构分类: 无机化合物 - 混合金属/非金属化合物 - 过渡金属氧阴离子化合物
• 英文名称: mercuric(II) nitrate monohydrate
• 英文别名: mercury(II) nitrate monohydrate；mercuric nitrate monohydrate；Mercury(2+);nitrate;hydrate
• 化学式: H₂O*Hg*2NO₃
• 分子量: 342.615
• InChiKey: XSDYMKAHAHCCKS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -1.07
• 重原子数：
  6
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  63.9
• 氢给体数：
  1
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  mercuric(II) nitrate monohydrate 在 oxalic acid 作用下， 以 水 为溶剂， 生成 草酸汞(II)
  参考文献：
  名称：

  Christensen, A. N.; Norby, P.; Hanson, J. C., Zeitschrift fur Kristallographie

  摘要：

  DOI：
• 作为产物：
  描述：

  在 sodium sulfide 作用下， 以 乙醇 、 水 为溶剂， 生成 mercuric(II) nitrate monohydrate 、
  参考文献：
  名称：

  A rhodamine based fluorescent probe for Hg2+ and its application to cellular imaging

  摘要：

  A new rhodamine-based fluorescent probe (Rh-F) for detection of Hg2+ ions was synthesized, which could bind Hg2+ in aqueous ethanol (7:3, v/v) at pH 7.0 with detectable change in color and fluorescence. The response is based on a ring opening reaction and formation of a 1:1 complex, while ring-opening process of spirolactam enables large fluorescent enhancement and colorimetric change upon the addition of Hg2+. The response is reversible and linear in the range between 200 nM and 1000 nM, with a detection limit of 4.2 nM. Selectivity and competition experiments with various other metal ion revealed that Rh-F possesses highly selective fluorescent response to Hg2+. Furthermore, the probe was successfully applied to fluorescent imaging of Hg2+ in L-929 cells confirm that Rh-F can be used as a fluorescent probe for monitoring Hg2+ in living cells. (C) 2013 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.saa.2012.12.079
• 作为试剂：
  描述：

  1-硝基-2-[2-(2-硝基苯基)乙炔基]苯 在 mercuric(II) nitrate monohydrate 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 反应 1.0h， 以32%的产率得到2-nitrobenzyl 2-nitrophenyl ketone
  参考文献：
  名称：

  Synthesis of α-Diketones from Alkylaryl- and Diarylalkynes Using Mercuric Salts

  摘要：

  Both alkylarylalkynes and diarylalkynes 1 are converted into the alpha-diketones 2 in good yield by the use of mercuric salts, e.g., mercuric nitrate hydrate or mercuric triflate, in the presence of water. Other mercuric salts, e.g., sulfate, chloride, acetate, or trifluoroacetate, do not provide the diketone product. A possible mechanism is proposed.

  DOI：

  10.1021/ol500592m

文献信息

• Mercury and methylmercury complexes with a triazine-3-thione ligand
  作者：Elena López-Torres、Ma Antonia Mendiola、César J. Pastor

  DOI：10.1016/j.poly.2005.10.013

  日期：2006.4

  different from the ones that have been previously reported, where the ligand acts as bidentate NS or bidentate NS bridging via the sulphur atom, and unusual behaviour for a triazine ligand. Complexes have been characterised by mass spectrometry, IR, multinuclear (1H, 13C) NMR, and X-ray diffraction. The redox behaviour was explored by cyclic voltammetry and both complexes show Hg(II)/Hg(I) processes

  摘要5-甲氧基-5,6-二苯基-4,5-二氢-2H- [1,2,4]三嗪-3-硫酮LH2OCH3与Hg（NO3）2·H2O和HgMeCl的反应得到单体化合物，其中三嗪失去甲氧基并通过硫原子与汞结合，起单齿的作用。在两个配合物中，金属离子周围的配位数为2，呈线性排列。这种配位模式不同于先前报道的配位模式，在配位模式中配体充当双齿NS或通过硫原子桥接的双齿NS，并且对于三嗪配体而言具有异常的行为。配合物已通过质谱，IR，多核（1H，13C）NMR和X射线衍射进行了表征。通过循环伏安法探讨了氧化还原行为，并且两种配合物均显示出Hg（II）/ Hg（I）过程。
• Binuclear and polymeric Hg(II) complexes of an ambidentate phosphorus ylide: Synthesis, crystal structure, antibacterial activity, and theoretical studies
  作者：Seyyed Javad Sabounchei、Faeze Kazemi Andalib、Marjan Hosseinzadeh、Asieh Sedghi、Ali Hashemi、Roya Karamian、Kristof Van Hecke

  DOI：10.1002/aoc.5265

  日期：2020.1

  resonance spectroscopic methods, which confirmed the coordination of ylide to the metal center through the ylidic carbon atom. Single‐crystal X‐ray structures of phosphorus ylide Y and polymeric complex 4 were also determined and the crystallographic data of complex 4 showed that the title complex has an infinite one‐dimensional structure. Furthermore, the electronic and molecular structures of complexes

  新的α-酮稳定的磷内酯Ph 3 PCHC（O）PhCN（Y）的合成方法是，将三苯基膦加到2-溴4'-氰基苯乙酮中，然后用10％的NaOH处理。配体（Y）与卤化汞（II）的甲醇溶液在温和条件下反应生成双核络合物[Y·HgX 2 ] 2 [X = Cl（1），Br（2），I（3）]。新型的有机/无机复合聚合物[Hg（NO 3）2（Y）] n（4）是通过硝酸汞（II）与磷酰磷Y的反应合成的。合成的化合物通过傅立叶变换红外光谱，1 H，31 P和13 C核磁共振波谱方法进行了表征，证实了叶立德通过碘碳原子与金属中心的配位。磷的单晶X射线结构叶立德ÿ和聚合物复合4还测定和复杂的晶体学数据4显示的标题配合物具有无限的一维结构。此外，复合物的电子和分子结构1 - 3在理论的BP86 / DEF2-SVP水平进行了研究，表明对于C→M键长增加的趋势：汞[Y→HgX 2 ] 2（X = Cl，Br，I）络合物中的2
• Cobaltocenium Carboxylate Transition Metal Complexes: Synthesis, Structure, Reactivity, and Cytotoxicity
  作者：Stefan Vanicek、Holger Kopacka、Klaus Wurst、Stefan Vergeiner、Luciano Oehninger、Ingo Ott、Benno Bildstein

  DOI：10.1002/zaac.201500033

  日期：2015.6

  is observed – from simple monomeric homoleptic complexes to heteroleptic dimeric, trimeric, and polymeric compounds, as shown by X-ray diffraction of 11 compounds. Chemically, thermal decarboxylation was investigated aiming at the formation of cobaltocenium-carbene transition metal complexes, in analogy to such chemistry of imidazolium carboxylate betaines. Cytotoxicity studies of cobaltocenium carboxylate

  Cobaltocenium carboxylate 是一种不寻常的甜菜碱，作为一种形式上中性的羧酸盐配体，具有晚期过渡金属中心，包括 Co2+、Ni2+、Cu2+、Ag+、Zn2+、Cd2+、Hg2+ 和 Rh+。在结构上，观察到了丰富的配位化学——从简单的单体均配复合物到杂配二聚体、三聚体和聚合化合物，如 11 种化合物的 X 射线衍射所示。在化学上，研究了热脱羧的目的是为了形成钴鎓-卡宾过渡金属配合物，类似于咪唑鎓羧酸甜菜碱的这种化学。进行了钴茂羧酸过渡金属配合物的细胞毒性研究，以评估这些化合物的药用生物有机金属潜力。虽然钴酸钴是非活性的，但它与 Ag+、Cd2+、
• The reaction of mercuric salts with dimethyl bicyclo[2.2.2]octa-2,5-diene-5,6-dicarboxylate
  作者：T. N. Sokolova、O. V. Vasil'eva、Yu. K. Grishin、D. V. Bazhenov、N. V. Malisova、V. R. Kartashov

  DOI：10.1007/bf00699199

  日期：1993.9

  The regioselectivity and stereochemistry of the reaction of mercuric salts with dimethyl bicyclo[2.2.2.]octa-2,5-diene-5,6-dicarboxylate were studied in different solvents. The factors determining the reaction regioselectivity were considered.

  在不同溶剂中研究了汞盐与双环[2.2.2.]octa-2,5-diene-5,6-dicarboxylate 反应的区域选择性和立体化学。考虑了决定反应区域选择性的因素。
• Monomercurated acetic acid. The crystal structure of NO3HgCH2COOH
  作者：D. Grdenić、B. Korpar-Čolig、D. Matković-Čalogović、M. Sikirica、Z. Popović

  DOI：10.1016/0022-328x(91)86002-8

  日期：1991.7

  Mercuration of acetic acid with mercuric acetate gives a condensation polymer of monomercurated acetic acid, CH3COO[HgCH2COO]nH, with n ≅ 10, which is soluble in alkali. The hydroxymercurioacetic acid polymer, OH[HgCH2COO]nH·H2O, with n ≅ 10, separates when the alkaline solution is treated with carbon dioxide, and treatment of this with hydrochloric and nitric acid gives ClHgCH2COOH and NO3HgCH2COOH

  乙酸与乙酸汞的水合反应制得的单体固化的乙酸缩合聚合物CH 3 COO [HgCH 2 COO] n H为n = 10，可溶于碱。当碱性溶液用二氧化碳处理时，羟基汞乙酸聚合物OH [HgCH 2 COO] n H·H 2 O分离，n = 10，然后用盐酸和硝酸处理，得到ClHgCH 2 COOH和NO 3分别为HgCH 2 COOH。