4-叔丁基环己基异丁烯酸酯 | 46729-07-1

• 物质功能分类: 医药中间体 - 原料药中间体
• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 中文名称: 4-叔丁基环己基异丁烯酸酯
• 中文别名: 2-甲基-2-丙烯酸-4-(1,1-二甲基乙基)环己基酯
• 英文名称: 4-tert-Butylcyclohexyl methacrylate
• 英文别名: (4-tert-butylcyclohexyl) 2-methylprop-2-enoate
• CAS: 46729-07-1
• 化学式: C₁₄H₂₄O₂
• 分子量: 224.34
• InChiKey: PILKNUBLAZTESB-UHFFFAOYSA-N

物化性质

• 熔点：
  30.5-31℃
• 沸点：
  277.3±9.0℃ (760 Torr)
• 密度：
  0.93±0.1 g/cm3 (20 ºC 760 Torr)
• 闪点：
  111.0±16.1℃
• LogP：
  6.07 at 30℃

计算性质

• 辛醇/水分配系数(LogP)：
  4.3
• 重原子数：
  16
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.79
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

文献信息

• THERMOPLASTIC POLYMER COMPOSITION AND MOLDED PRODUCT
  申请人：MAWATARI Masaaki

  公开号：US20120065332A1

  公开（公告）日：2012-03-15

  A thermoplastic polymer composition capable of exhibiting excellent impact resistance, durability and destaticizing property containing (A) 50 to 95% by mass of an aliphatic polyester-based resin and (B) 5 to 50% by mass of a block copolymer of (B1) a hard segment block with at least one of a polyamide, polyester, polyolefin or polyurethane, and (B2) a soft segment block having an ether bond.

  一种热塑性聚合物组合物，能够表现出优异的抗冲击性、耐久性和除静电性，包含（A）50至95重量％的脂肪族聚酯基树脂和（B）5至50重量％的嵌段共聚物，其中（B1）是具有聚酰胺、聚酯、聚烯烃或聚氨酯中至少一种的硬段块，（B2）是具有醚键的软段块。
• POLYMERIZABLE COMPOUND AND CURABLE COMPOSITION COMPRISING SAME
  申请人：Ooga Kazuhiko

  公开号：US20120232183A1

  公开（公告）日：2012-09-13

  Provided are a polymerizable compound, a photocurable composition, and a photocurable moisture-proof insulating coating material for mounting circuit boards, which reduce environmental impact, excel in surface curability at low irradiation dose, and have high adhesion to substrate materials. The compound according to the present invention has a structural unit derived from a dimerdiol and has, as an end group, a group represented by formula (1): wherein R 1 represents H or CH 3 and R 2 represents a hydrocarbon group having 2 to 12 carbon atoms, at an end thereof. Preferably, the compound has, as end groups, the group represented by formula (1) and a group represented by formula (2): wherein R 3 s each independently represent CH 3 or CH 2 CH 3 , and R 4 represents a hydrocarbon group having 3 to 9 carbon atoms, at the end thereof. The structure having the structural unit derived from a dimerdiol is preferably represented by formula (3):

  本发明提供了一种可聚合化合物、一种光固化组合物和一种用于安装电路板的光固化防潮绝缘涂料材料，其减少环境影响，在低辐射剂量下具有优异的表面固化性能，并且对基材具有高粘附性。本发明的化合物具有从二聚醇衍生的结构单元，并具有式（1）所表示的基团作为末端基团，其中R1代表H或CH3，R2代表具有2到12个碳原子的烃基，在其末端。最好的情况是，该化合物具有由式（1）和式（2）所表示的基团作为末端基团：其中R3各自独立地表示 或CH2 ，R4表示具有3到9个碳原子的烃基，在其末端。具有从二聚醇衍生的结构单元的结构最好是由式（3）所表示的。
• POLYMERIZABLE COMPOSITION, POLYMERIZATION PRODUCT, IMAGE DISPLAY DEVICE, AND METHOD FOR PRODUCING SAME
  申请人：SHOWA DENKO K.K.

  公开号：US20150030836A1

  公开（公告）日：2015-01-29

  In relation to a polymerizable composition for forming a transparent optical resin layer to be interposed between an image display section of an image display device and a light-transmissive protective section thereof, the present invention provides a polymerizable composition that does not give rise to display defects caused by the deformation of the image display section, enables high-luminance, high-contrast image displaying, has excellent heat resistance, and also has a low dielectric constant. This polymerizable composition comprises: (1) a urethane (meth)acrylate obtained by reacting a hydrogenated polyolefin polyol and a compound having an isocyanato group and a (meth)acryloyl group; (2) a (meth)acryloyl-group-containing compound having a hydrocarbon group with a carbon number of 6 or greater; and (3) a photopolymerization initiator.

  本发明涉及一种聚合物组合物，用于形成透明光学树脂层，以介于图像显示装置的图像显示部分和其透光保护部分之间。该聚合物组合物不会因为图像显示部分的变形而产生显示缺陷，能够实现高亮度、高对比度的图像显示，具有优异的耐热性，同时具有低介电常数。该聚合物组合物包括：(1)通过反应氢化聚烯烃多元醇和具有异氰酸酯基和(meth)丙烯酰基的化合物得到的聚氨酯(meth)丙烯酸酯；(2)具有碳数大于等于6的碳氢基团的(meth)丙烯酰基含有化合物；以及(3)光聚合引发剂。
• CURABLE COMPOSITION
  申请人：SHOWA DENKO K.K.

  公开号：US20140309326A1

  公开（公告）日：2014-10-16

  Provided are a polymerizable compound, a photocurable composition, and a photocurable moisture-proof insulating coating material for mounting circuit boards, which reduce environmental impact, excel in surface curability at low irradiation dose, and have high adhesion to substrate materials. The compound according to the present invention has a structural unit derived from a dimerdiol and has, as an end group, a group represented by formula (1): wherein R 1 represents H or CH 3 and R 2 represents a hydrocarbon group having 2 to 12 carbon atoms, at an end thereof. Preferably, the compound has, as end groups, the group represented by formula (1) and a group represented by formula (2): wherein R 3 s each independently represent CH 3 or CH 2 CH 3 , and R 4 represents a hydrocarbon group having 3 to 9 carbon atoms, at the end thereof. The structure having the structural unit derived from a dimerdiol is preferably represented by formula (3):

  本发明提供了一种可聚合化合物、一种光固化组合物和一种用于安装电路板的光固化防潮绝缘涂料材料，其可降低环境影响，在低辐照剂量下具有优异的表面固化性能，并且对基底材料具有高粘附性。根据本发明，该化合物具有源自二元醇二聚体的结构单元，并且具有式（1）所表示的基团作为末端基团。其中，R1表示H或CH3，R2表示具有2到12个碳原子的烃基，在其末端。最好的情况是，该化合物具有式（1）所表示的基团和式（2）所表示的基团作为末端基团。其中，R3分别独立表示 或CH2 ，R4表示具有3到9个碳原子的烃基，在其末端。具有源自二元醇二聚体的结构单元的结构最好用式（3）表示：
• BLOCK COPOLYMERS WITH HIGH FLORY-HUGGINS INTERACTION PARAMETERS FOR BLOCK COPOLYMER LITHOGRAPHY
  申请人：Wisconsin Alumni Research Foundation

  公开号：US20150099109A1

  公开（公告）日：2015-04-09

  Block copolymers for use in block copolymer lithography, self-assembled films of the block copolymers and methods for polymerizing the block copolymers are provided. The block copolymers are characterized by high Flory-Huggins interaction parameters (χ). The block copolymers can be polymerized from protected hydroxystyrene monomers or from tert-butyl styrene and 2-vinylpyridine monomers.

  提供用于块共聚物光刻的块共聚物、块共聚物自组装薄膜以及聚合块共聚物的方法。这些块共聚物具有高Flory-Huggins相互作用参数(χ)。这些块共聚物可以从保护羟基苯乙烯单体或叔丁基苯乙烯和2-乙烯基吡啶单体聚合而成。