N,N'-di(2-(propoxy)ethyl)perylene-3,4,9,10-tetracarboxylic diimide | 59736-89-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 菲及其衍生物
• 英文名称: N,N'-di(2-(propoxy)ethyl)perylene-3,4,9,10-tetracarboxylic diimide
• 英文别名: N,N'-di(propoxyethyl)-perylene-3,4,9,10-tetracarboxylic diimide；2,9-bis-(2-propoxy-ethyl)-anthra[2,1,9-def;6,5,10-d'e'f']diisoquinoline-1,3,8,10-tetraone；7,18-Bis(2-propoxyethyl)-7,18-diazaheptacyclo[14.6.2.22,5.03,12.04,9.013,23.020,24]hexacosa-1(23),2,4,9,11,13,15,20(24),21,25-decaene-6,8,17,19-tetrone；7,18-bis(2-propoxyethyl)-7,18-diazaheptacyclo[14.6.2.22,5.03,12.04,9.013,23.020,24]hexacosa-1(23),2,4,9,11,13,15,20(24),21,25-decaene-6,8,17,19-tetrone
• CAS: 59736-89-9
• 化学式: C₃₄H₃₀N₂O₆
• 分子量: 562.622
• InChiKey: UDGIOYRZXUOZPP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.2
• 重原子数：
  42
• 可旋转键数：
  10
• 环数：
  7.0
• sp3杂化的碳原子比例：
  0.29
• 拓扑面积：
  93.2
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为产物：
  描述：

  2-N-丙氧基乙胺 、 3,4,9,10-苝四羧酸二酐 在 咪唑 作用下， 反应 4.0h， 生成 N,N'-di(2-(propoxy)ethyl)perylene-3,4,9,10-tetracarboxylic diimide
  参考文献：
  名称：

  Nanobelt Self-Assembly from an Organic n-Type Semiconductor:  Propoxyethyl-PTCDI

  摘要：

  Nanobelt structures have been fabricated for an n-type semiconductor molecule, N,N'-di(propoxyethyl)perylene-3,4,9,10-tetracarboxylic diimide (PTCDI). The short alkyloxy side chain not only affords effective pi-pi stacking in polar solvents for self-assembling but also provides sufficient solubility in nonpolar solvents for solution processing. As revealed by both AFM and electron microscopies, the nanobelts have an approximately rectangular cross section, with a typical thickness of about 100 nm and a width in the range of 300-500 nm. The length of the nanobelts ranges from 10 to a few tens of micrometers. The highly organized molecular packing (uniaxial crystalline phase) has been deduced from the measurement of electron diffraction and polarized microscopy imaging. The detected optical axis is consistent with the one-dimensional stacking of the molecules.

  DOI：

  10.1021/ja052940v

文献信息

• SENSOR COMPOUNDS AND ASSOCIATED METHODS AND DEVICES
  申请人：UNIVERSITY OF UTAH RESEARCH FOUNDATION

  公开号：US20180201612A1

  公开（公告）日：2018-07-19

  Methods of detecting a non-explosive analyte can include exposing a sensor compound to a non-explosive analyte and displaying a change in the sensor compound upon exposure of the sensor compound to the non-explosive analyte. A variety of sensor compounds for detecting a target analyte, including both explosive and non-explosive analytes, is also described. Sensor devices for detecting a target analyte can include a substrate and a sensor compound positioned on the substrate in a plurality of detection zones.

  检测非爆炸性分析物的方法可以包括将传感器化合物暴露于非爆炸性分析物，并在传感器化合物暴露于非爆炸性分析物时显示传感器化合物的变化。还描述了用于检测目标分析物（包括爆炸性和非爆炸性分析物）的各种传感器化合物。用于检测目标分析物的传感器设备可以包括底板和位于底板上的传感器化合物，其位于多个检测区域中。
• [EN] SENSOR COMPOUNDS AND ASSOCIATED METHODS AND DEVICES<br/>[FR] COMPOSÉS DE DÉTECTION ET PROCÉDÉS ET DISPOSITIFS ASSOCIÉS
  申请人：UNIV UTAH RES FOUND

  公开号：WO2017008074A1

  公开（公告）日：2017-01-12

  Methods of detecting a non-explosive analyte can include exposing a sensor compound to a non-explosive analyte and displaying a change in the sensor compound upon exposure of the sensor compound to the non-explosive analyte. A variety of sensor compounds for detecting a target analyte, including both explosive and non-explosive analytes, is also described. Sensor devices for detecting a target analyte can include a substrate and a sensor compound positioned on the substrate in a plurality of detection zones.
• Nanobelt Self-Assembly from an Organic n-Type Semiconductor:  Propoxyethyl-PTCDI
  作者：Kaushik Balakrishnan、Aniket Datar、Randy Oitker、Hao Chen、Jianmin Zuo、Ling Zang

  DOI：10.1021/ja052940v

  日期：2005.8.1

  Nanobelt structures have been fabricated for an n-type semiconductor molecule, N,N'-di(propoxyethyl)perylene-3,4,9,10-tetracarboxylic diimide (PTCDI). The short alkyloxy side chain not only affords effective pi-pi stacking in polar solvents for self-assembling but also provides sufficient solubility in nonpolar solvents for solution processing. As revealed by both AFM and electron microscopies, the nanobelts have an approximately rectangular cross section, with a typical thickness of about 100 nm and a width in the range of 300-500 nm. The length of the nanobelts ranges from 10 to a few tens of micrometers. The highly organized molecular packing (uniaxial crystalline phase) has been deduced from the measurement of electron diffraction and polarized microscopy imaging. The detected optical axis is consistent with the one-dimensional stacking of the molecules.