2-[3-(2-hydroxyphenyl)propyl]phenol | 29337-79-9

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 直链 1,3-二芳基丙烷
• 英文名称: 2-[3-(2-hydroxyphenyl)propyl]phenol
• 英文别名: 2,2'-(propane-1,3-diyl)diphenol；(1,3-o-hydroxyphenyl)propane；o,o'-Bis-1,3-trimethylenphenol；o,o'-Trimethylenphenol；2,2'-propanediyl-di-phenol；2,2'-Propandiyl-di-phenol；2.2'-Trimethylen-diphenol
• CAS: 29337-79-9
• 化学式: C₁₅H₁₆O₂
• 分子量: 228.291
• InChiKey: BCCUXYYWOOECKZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4
• 重原子数：
  17
• 可旋转键数：
  4
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.2
• 拓扑面积：
  40.5
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  2-[3-(2-hydroxyphenyl)propyl]phenol 在 Grubbs catalyst first generation 、 potassium carbonate 作用下， 以 二氯甲烷 、 丙酮 为溶剂， 反应 26.0h， 生成 (E)-9,15,16,17-tetrahydro-6H-dibenzo[g,l][1,6]dioxacyclotridecine
  参考文献：
  名称：

  闭环易位反应可访问的13元杂环中烯烃双键的立体化学

  摘要：

  通过闭环复分解（RCM）反应合成了曼扎明生物碱核心结构的13元杂环类似物。评估了远程杂原子（N，O，S）对使用第一和第二代钌卡宾络合物在RCM反应中形成的烯烃双键的E / Z立体化学的影响。研究表明，RCM反应是动力学控制的，杂原子影响双键的立体化学。

  DOI：

  10.1016/j.tetlet.2012.09.065
• 作为产物：
  描述：

  trans-2,2'-dihydroxychalcone 在 异丙醇 作用下， 反应 16.0h， 生成 2-[3-(2-hydroxyphenyl)propyl]phenol
  参考文献：
  名称：

  闭环易位反应可访问的13元杂环中烯烃双键的立体化学

  摘要：

  通过闭环复分解（RCM）反应合成了曼扎明生物碱核心结构的13元杂环类似物。评估了远程杂原子（N，O，S）对使用第一和第二代钌卡宾络合物在RCM反应中形成的烯烃双键的E / Z立体化学的影响。研究表明，RCM反应是动力学控制的，杂原子影响双键的立体化学。

  DOI：

  10.1016/j.tetlet.2012.09.065

文献信息

• Palladium‐Catalyzed Propargylic [n+2] Cycloaddition: An Efficient Strategy for Construction of Benzo‐Fused Medium‐Sized Heterocycles
  作者：Zhen‐Ting Liu、Xiang‐Ping Hu

  DOI：10.1002/adsc.201801359

  日期：——

  No Abstract

  没有摘要
• PROCESSES FOR PRODUCING RAW POLYCARBONATE RESIN MATERIAL AND PRODUCING POLYCARBONATE RESIN
  申请人：IDEMITSU PETROCHEMICAL CO., LTD.

  公开号：EP1178068A1

  公开（公告）日：2002-02-06

  The invention relates to an inexpensive and simple method for producing a starting material for polycarbonate resin and for producing polycarbonate resin. In the method for producing a starting material for polycarbonate resin production through interfacial polymerization, (I) a molten bisphenol compound is mixed and dissolved in an aqueous alkali solution at 20 to 80°C, or (II) it is, without being solidified, directly mixed with water to be in liquid at a temperature not higher than the melting point of the bisphenol compound, and then dissolved in an aqueous alkali solution.

  本发明涉及一种生产聚碳酸酯树脂起始材料和生产聚碳酸酯树脂的廉价而简单的方法。在通过界面聚合生产聚碳酸酯树脂起始原料的方法中，(I) 将熔融双酚化合物混合并溶解在 20 至 80°C 的碱水溶液中，或 (II) 在不高于双酚化合物熔点的温度下将其与水直接混合成液态，然后溶解在碱水溶液中。
• Process for producing raw polycarbonate resin material and producing polycarbonate resin
  申请人：IDEMITSU PETROCHEMICAL CO., LTD.

  公开号：EP1361241A1

  公开（公告）日：2003-11-12

  The invention relates to an inexpensive and simple method for producing a starting material for polycarbonate resin and for producing polycarbonate resin. In the method for producing a starting material for polycarbonate resin production through interfacial polymerization, a molten bisphenol compound is    without being solidified, directly mixed with water to be in liquid at a temperature not higher than the melting point of the bisphenol compound, and then dissolved in an aqueous alkali solution.

  本发明涉及一种生产聚碳酸酯树脂起始材料和生产聚碳酸酯树脂的廉价而简单的方法。在通过界面聚合生产聚碳酸酯树脂起始材料的方法中，熔融双酚化合物 在不高于双酚化合物熔点的温度下，将熔融双酚化合物与水直接混合成液态，然后溶解在碱水溶液中。
• PROCESSES FOR PRODUCTION OF POWDERED FLUORORESINS BEARING CURABLE FUNCTIONAL GROUPS AND COATING COMPOSITIONS CONTAINING THE SAME
  申请人：Asahi Glass Company, Limited

  公开号：EP1460090A1

  公开（公告）日：2004-09-22

  It is to provide a production process by which gelation can be prevented, in a case where a solvent is removed from a curable fluororesin to obtain a chief material resin, and then coating additives such as a curing agent are mixed to produce a powder coating composition, or in a case where a curable fluororesin, a curing agent and various additives are dissolved or dispersed in a solvent to prepare a raw material solution, and the solvent is removed from the raw material solution to directly produce a powder coating material. To a solution or dispersion of a curable fluorinated copolymer (A), a gelation inhibitor (B) is added, followed by mixing, or a gelation inhibitor (B), a curing agent (C) and as the case requires, various additives (D) are added, followed by mixing, and the solution or dispersion is supplied to a thin-film vacuum evaporator to remove the solvent.

  其目的是提供一种可防止凝胶化的生产工艺，即从可固化氟树脂中去除溶剂以获得主材料树脂，然后混合固化剂等涂料添加剂以生产粉末涂料组合物，或者将可固化氟树脂、固化剂和各种添加剂溶解或分散在溶剂中以制备原料溶液，然后从原料溶液中去除溶剂以直接生产粉末涂料材料。 在可固化含氟共聚物（A）的溶液或分散液中加入凝胶化抑制剂（B），然后混合，或加入凝胶化抑制剂（B）、固化剂（C）和各种添加剂（D）（视情况需要），然后混合，并将溶液或分散液提供给薄膜真空蒸发器以去除溶剂。
• Processes for producing a fluororesin powder having curable functional groups and its coating composition
  申请人：ASAHI GLASS COMPANY LIMITED

  公开号：US20040225060A1

  公开（公告）日：2004-11-11

  It is to provide a production process by which gelation can be prevented, in a case where a solvent is removed from a curable fluororesin to obtain a chief material resin, and then coating additives such as a curing agent are mixed to produce a powder coating composition, or in a case where a curable fluororesin, a curing agent and various additives are dissolved or dispersed in a solvent to prepare a raw material solution, and the solvent is removed from the raw material solution to directly produce a powder coating material. To a solution or dispersion of a curable fluorinated copolymer (A), a gelation inhibitor (B) is added, followed by mixing, or a gelation inhibitor (B), a curing agent (C) and as the case requires, various additives (D) are added, followed by mixing, and the solution or dispersion is supplied to a thin-film vacuum evaporator to remove the solvent.

  其目的是提供一种可防止凝胶化的生产工艺，即从可固化氟树脂中去除溶剂以获得主材料树脂，然后混合固化剂等涂料添加剂以生产粉末涂料组合物，或者将可固化氟树脂、固化剂和各种添加剂溶解或分散在溶剂中以制备原料溶液，然后从原料溶液中去除溶剂以直接生产粉末涂料材料。 在可固化含氟共聚物（A）的溶液或分散液中加入凝胶化抑制剂（B），然后混合，或加入凝胶化抑制剂（B）、固化剂（C）和各种添加剂（D）（视情况需要），然后混合，并将溶液或分散液提供给薄膜真空蒸发器以去除溶剂。