1-Phenyl-2--ethandion | 98030-00-3

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 直链 1,3-二芳基丙烷
• 英文名称: 1-Phenyl-2--ethandion
• 英文别名: Phenyl-2-chinolyl-diketon；1-phenyl-2-quinolin-2-ylethane-1,2-dione；phenyl-quinolin-2-yl-ethanedione
• CAS: 98030-00-3
• 化学式: C₁₇H₁₁NO₂
• 分子量: 261.28
• InChiKey: VYYTVLBMFNKLTI-UHFFFAOYSA-N

物化性质

• 熔点：
  140-143 °C
• 沸点：
  454.1±18.0 °C(Predicted)
• 密度：
  1.257±0.06 g/cm3(Predicted)

反应信息

• 作为产物：
  描述：

  在 水 、 碘 、 sodium dodecyl-sulfate 作用下， 反应 0.58h， 以82%的产率得到1-Phenyl-2--ethandion
  参考文献：
  名称：

  Ultrasound-assisted synthesis of aromatic 1,2-diketones from oximinoketones under neutral conditions in aqueous media

  摘要：

  We report a convenient, neutral, and facile methodology for the synthesis of aromatic 1,2-diketones from the corresponding oximinoketones in the presence of I-2/SDS/water system under ultrasound-assisted conditions. Furthermore, a series of compounds were synthesized and characterized by melting point, IR, NMR, MS, and elemental analysis. Utilization of easy reaction conditions, very high to excellent yields, and short reaction times makes this manipulation potentially very useful. (C) 2011 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ultsonch.2011.05.011