| 339557-14-1

• 分子结构分类: 有机化合物 - 有机氧化合物
• CAS: 339557-14-1
• 化学式: C₁₆H₁₃AgN₂O₃*H₂O
• 分子量: 407.174
• InChiKey: QIIILRAXZSRMAZ-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  8-羟基喹啉 、 sodium o-aminobenzoate 、 silver nitrate 以 乙醇 、 水 为溶剂， 生成
  参考文献：
  名称：

  摘要：

  It was found by elementary, crystal optics, X-ray diffraction analyses, and IR- and UV-spectroscopy methods that the reaction of Ag(I) with anthranilic acid (HAnt) and oxine (Ox) (at the 1 : 1 : 1 ratio of the components) yielded a mixed-ligand complex AgOxAnt .H2O. It was shown that Ag(I) coordinated oxine in a neutral form and was bound with the nitrogen atom of Ox and with the oxygen atom of the deprotonated carboxylic group of Ant. An amino group of Ant(-) was not coordinated by the silver atom. The complex isolated is highly soluble in 2N solutions of nitric acid and ammonia and in concentrated sulfuric acid.

  DOI：

  10.1023/a:1009501211223