1-acetyl-3-vinyladamantane | 423166-16-9

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 1-acetyl-3-vinyladamantane
• 英文别名: 1-(3-Ethenyl-1-adamantyl)ethanone
• CAS: 423166-16-9
• 化学式: C₁₄H₂₀O
• 分子量: 204.312
• InChiKey: WKBCFYDGQJCGLF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.2
• 重原子数：
  15
• 可旋转键数：
  2
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.79
• 拓扑面积：
  17.1
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  3-butanedione 、 1-(1-金刚烷基)乙烯 生成 1-acetyl-3-vinyladamantane
  参考文献：
  名称：

  摘要：

  DOI：

文献信息

• Monomer having electron-withdrawing group and process for preparing the same
  申请人：——

  公开号：US20030059710A1

  公开（公告）日：2003-03-27

  A monomer containing an electron-withdrawing group of the present invention is represented by following Formula (a), (b) or (c): 1 wherein A 1 , A 2 , and A 3 are each a ring; R a , R b , R c , and R u are the same or different and are each a hydrogen atom or organic group; at least one of R s , R w and R v , at least one of R t and R w1 , and at least one of the two R w2 s are each an electron-withdrawing group, and the others are each a hydrogen atom or organic group; W 1 is a single bond or linkage group; and n denotes an integer of 2 to 25, where at least two of R a , R b , R c , R s , R t , R u , R v , R w , R w1 , R w2 , W 1 , and carbon atoms constituting ring A 1 , carbon atoms constituting ring A 2 , and carbon atoms constituting ring A 3 may be combined to form a ring, respectively. The electron-withdrawing groups in R s , R t , R v , R w , R w1 , and R w2 are, for example, groups each containing a fluorine atom. The monomer is useful as a raw material for photoresist polymeric compounds.

  本发明的含有电子吸引基团的单体由以下化学式(a)、(b)或(c)表示：其中A1、A2和A3各自为一个环；Ra、Rb、Rc和Ru相同或不同，各自为氢原子或有机基团；Rs、Rw和Rv中至少有一个，Rt和Rw1中至少有一个，两个Rw2中至少有一个为电子吸引基团，其他的为氢原子或有机基团；W1为单键或连接基团；n表示2到25的整数，其中至少有两个Ra、Rb、Rc、Rs、Rt、Ru、Rv、Rw、Rw1、Rw2、W1和构成环A1的碳原子、构成环A2的碳原子以及构成环A3的碳原子可以分别结合形成一个环。 Rs、Rt、Rv、Rw、Rw1和Rw2中的电子吸引基团，例如，是每个含有氟原子的基团。该单体可用作光刻胶聚合物化合物的原材料。
• MONOMERS HAVING ELECTRON-WITHDRAWING GROUPS AND PROCESSES FOR PREPARING THE SAME
  申请人：Daicel Chemical Industries, Ltd.

  公开号：EP1331216A1

  公开（公告）日：2003-07-30

  A monomer containing an electron-withdrawing group of the present invention is represented by following Formula (a), (b) or (c) : wherein A1, A2, and A3 are each a ring; Ra, Rb, Rc, and Ru are the same or different and are each a hydrogen atom or organic group; at least one of Rs, Rw and Rv, at least one of Rt and Rw1, and at least one of the two Rw2s are each an electron-withdrawing group, and the others are each a hydrogen atom or organic group; W1 is a single bond or linkage group; and n denotes an integer of 2 to 25, where at least two of Ra, Rb, Rc, Rs, Rt, Ru, Rv, Rw, Rw1, Rw2, W1, and carbon atoms constituting ring A1, carbon atoms constituting ring A2, and carbon atoms constituting ring A3 may be combined to form a ring, respectively. The electron-withdrawing groups in Rs, Rt, Rv, Rw, Rw1, and Rw2 are, for example, groups each containing a fluorine atom. The monomer is useful as a raw material for photoresist polymeric compounds.

  本发明中含有抽电子基团的单体由下式(a)、(b)或(c)表示： 其中 A1、A2 和 A3 各为一个环；Ra、Rb、Rc 和 Ru 相同或不同，各为一个氢原子或有机基团；Rs、Rw 和 Rv 中的至少一个，Rt 和 Rw1 中的至少一个，以及两个 Rw2 中的至少一个各为一个抽电子基团，其它各为一个氢原子或有机基团；W1是单键或连接基团；n表示2至25的整数，其中Ra、Rb、Rc、Rs、Rt、Ru、Rv、Rw、Rw1、Rw2、W1中的至少两个以及构成环A1的碳原子、构成环A2的碳原子和构成环A3的碳原子可分别组合成一个环。例如，Rs、Rt、Rv、Rw、Rw1 和 Rw2 中的抽电子基团是各自含有一个氟原子的基团。该单体可用作光阻聚合化合物的原料。
• US6949615B2
  申请人：——

  公开号：US6949615B2

  公开（公告）日：2005-09-27