| 368863-37-0

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• CAS: 368863-37-0
• 化学式: C₆H₁₄N₆NiO₆
• 分子量: 324.904
• InChiKey: BXQMTXGLTBXEAB-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  nickel(II) chloride hexahydrate 、 胍基乙酸 在 氢氧化钾 、 硝酸 作用下， 以 水 为溶剂， 生成 、
  参考文献：
  名称：

  STUDY OF NEW COMPLEXES OF CHROMIUM(III), COBALT(II), NICKEL(II), COPPER(II), AND ZINC(II) WITH GUANIDINOACETIC ACID, THE PRECURSOR OF CREATINE

  摘要：

  Guanidinoacetic acid (H(2)Gaa), the essential precursor of creatine, plays an important role in our organism. However, H(2)Gaa interaction with metal ions has not yet been studied. We have previously studied H(2)Gaa complexation with some metallic ions in solution. In this study, Cr(III), Co(II), Ni(II), Cu(II) and Zn(II) complexes of H(2)Gaa were synthesized and characterized (C, H, N, thermogravimetric analyses, infrared spectroscopy). Electron paramagnetic resonance and ultraviolet spectroscopy were also used but in aqueous solutions at 25 degreesC. In all of the cases the coordinating atoms were the alpha-nitrogen and oxygen atoms. The most probable geometry of each of the complexes is cis-square-planar in Cu(HGaa)(2), tetrahedral in Zn(H(2)Gaa)NO3Cl and octahedral in Cr(HGaa)(3), CoH(2)Gaa(HGaa)(2) and NiH(2)Gaa(HGaa)(2).

  DOI：

  10.1081/sim-100104857