N,N-bis(dimethylsilyl)allylamine | 25964-67-4

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: N,N-bis(dimethylsilyl)allylamine
• 英文别名: Bis-(N-dimethylsilyl)-allylamin；2-methyl-3-dimethylsilyl-2-sila-3-aza-5-hexene；2-methyl-2-sila-3-dimethylsilyl-3-aza-5-hexene；N,N-bis(dimethylsilyl)prop-2-en-1-amine
• CAS: 25964-67-4
• 化学式: C₇H₁₉NSi₂
• 分子量: 173.406
• InChiKey: JMXWYCKNTYDKAX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.44
• 重原子数：
  10
• 可旋转键数：
  4
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.71
• 拓扑面积：
  3.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  N,N-bis(dimethylsilyl)allylamine 以90%的产率得到
  参考文献：
  名称：

  Itsuno Shinichi, Koizumi Takahiro, Okumura Chisa, Ito Koichi, Synthesis, (1995) N 2, S 150-152

  摘要：

  DOI：
• 作为产物：
  描述：

  potassium bis(dimethylsilyl)amide 以88%的产率得到
  参考文献：
  名称：

  Itsuno Shinichi, Koizumi Takahiro, Okumura Chisa, Ito Koichi, Synthesis, (1995) N 2, S 150-152

  摘要：

  DOI：

文献信息

• Synthesis of Primary Amines Using Potassium 1,1,3,3-Tetramethyldisilazide as Aminating Agent of Alkyl Halides
  作者：Shinichi Itsuno、Takahiro Koizumi、Chisa Okumura、Koichi Ito

  DOI：10.1055/s-1995-3875

  日期：1995.2

  A one-pot synthesis of various primary amines is described. Potassium 1,1,3,3-tetramethyldisilazide, prepared from 1,1,3,3-tetramethyldisilazane and potassium hydride, reacts with alkyl bromides, iodides, tosylates, benzylic chlorides, and allylic chlorides to give the corresponding N,N-bis(dimethylsilyl)amines in high yields. Subsequent deprotection of the dimethylsilyl group was performed under mildly acidic conditions to afford primary amines. This method was also applied to the preparation of aminomethylated cross-linked polystyrene.

  描述了一种一锅合成各种一级胺的方法。由1,1,3,3-四甲基二硅氮烷和氢化钾制备的氢化钾1,1,3,3-四甲基二硅氮烷与烷基溴、碘、托基磺酸盐、苄基氯和烯丙基氯反应，产生相应的N,N-双(二甲基硅基)胺，产率很高。随后在温和酸性条件下去保护二甲基硅基，从而获得一级胺。该方法还应用于制备氨基甲基化交联聚苯乙烯。
• METHOD FOR PREPARING AMINOPROPYLSILANES
  申请人：WACKER CHEMIE AG

  公开号：US20210284666A1

  公开（公告）日：2021-09-16

  Aminopropylalkoxysilanes of the formula H 2 N—CR 2 R 3 —CHR 1 —CH 2 —SiR 4 R 5 (OR 6 )   I, are synthesized by hydrosilylating silazanes of the formulae and mixtures thereof, in the presence of a catalyst containing rhodium and/or iridium compounds, and then reacted with alcohol to form an aminopropylalkoxysilane.

  公式为H2N—CR2R3—CHR1—CH2—SiR4R5(OR6)的氨丙基烷氧基硅烷I，是在存在含铑和/或铱化合物催化剂的情况下，通过氢硅烷化硅氮烷及其混合物的方法合成的，然后与醇反应形成氨丙基烷氧基硅烷。
• Compounds containing 1-aza-3-oxa-4-silacyclohex-1-enyl groups, and
  申请人：Dow Corning Asia Ltd.

  公开号：US05446180A1

  公开（公告）日：1995-08-29

  Novel 1-aza-3-oxa-4-silacyclohex-1-ene compounds, and tautomers thereof, having utility as chemical modifiers or cross linkers for hydroxy-containing organic or inorganic substances are disclosed, said compounds being represented by the general formula (I) ##STR1## wherein R.sup.1 and R.sup.2 each independently denotes a monovalent organic group having 1 to 6 carbon atoms selected from the group consisting of saturated hydrocarbon groups and unsaturated hydrocarbon groups, R.sup.3 deontes an organic group having 1 to 30 carbon atoms selected from the group consisting of saturated hydrocarbon groups and unsaturated hydrocarbon groups, said R.sup.3 groups optionally containing a heteroatom selected from the group consisting of oxygen, nitrogen, sulfur, silicon, fluorine, chlorine, bromine and iodine, Me denotes a methyl radical and n is an integer having a value of 1 to 4.

  本发明揭示了一种 Novel 1-aza-3-oxa-4-silacyclohex-1-ene 化合物及其互变异构体，其具有作为羟基含有的有机或无机物质的化学修饰剂或交联剂的效用，所述化合物由通式 (I) 表示：##STR1## 其中，R.sup.1 和 R.sup.2 各自独立地表示选自饱和碳氢基团和不饱和碳氢基团的 1 至 6 个碳原子的一价有机基团，R.sup.3 表示选自饱和碳氢基团和不饱和碳氢基团的 1 至 30 个碳原子的有机基团，所述 R.sup.3 基团可选包含选自氧、氮、硫、硅、氟、氯、溴和碘的杂原子，Me 表示甲基基团，n 是一个整数，其值为 1 至 4。
• Kozyukov, V. P.; Kozyukov, Vik. P.; Mironov, V. F., Journal of general chemistry of the USSR, 1983, vol. 53, # 9, p. 1887 - 1892
  作者：Kozyukov, V. P.、Kozyukov, Vik. P.、Mironov, V. F.

  DOI：——

  日期：——
• Mironov,V.F. et al., Doklady Chemistry, 1970, vol. 190, p. 17 - 20
  作者：Mironov,V.F. et al.

  DOI：——

  日期：——