[Cu(acetate)(5-hydroxy-2-[[2-(2-hydroxyetino)ethylimino]methyl]phenol(-1H))] | 1338696-82-4

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: [Cu(acetate)(5-hydroxy-2-[[2-(2-hydroxyetino)ethylimino]methyl]phenol(-1H))]
• CAS: 1338696-82-4
• 化学式: C₁₃H₁₈CuN₂O₅
• 分子量: 345.842
• InChiKey: KVPHMQMWFQBMHF-LIYVDSPJSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  copper diacetate 、 羟乙基乙二胺 、 2,4-二羟基苯甲醛 以 乙醇 为溶剂， 以82%的产率得到[Cu(acetate)(5-hydroxy-2-[[2-(2-hydroxyetino)ethylimino]methyl]phenol(-1H))]
  参考文献：
  名称：

  Synthesis, structure, and properties of coordination compounds of copper(II) acetate with substituted 2-{[2-(2-hydroxyethylamino)ethylimino]methyl}phenol

  摘要：

  Salicylic, 5-chloro-5-bromo-5-nitro-, 3-methoxysalicylic, 2-hydroxy-1-naphthoic aldehydes and 2,3-, 2,4-, and 2,5-dihydroxybenzaldehyde were shown to react in ethanol with 2-(2-aminoethylamino)ethanol in the presence of copper acetate hydrate forming coordination compounds Cu(L1-9)CH3COO {HL1-8, 2-([2-(2-hydroxyethylamino)ethylimino]methyl}phenol (HL1) and respective chloro-(HL2), bromo-(HL3), nitro-(HL4), methoxy- (HL8), or hydroxy-substituted (HL5-7); HL9, 2-{[2-(2-hydroxyethylamine)ethylimino]methylnaphthol)}. Structure of the complex Cu(L-3)CH3COO was determined by X-ray diffraction analysis. Coordination polyhedron of its central atom is a distorted tetragonal bipyramid with (4+1+1) modes of coordinating the copper atom. The bipyramid base is formed by the atoms of phenol oxygen and of azomethine and imine nitrogen atoms of the ligand (HL3) and the oxygen atom of the acetate ion. Axial apices of the bipyramid are occupied by the alcohol oxygen atoms of the azomethine (HL3) and the second oxygen atom of the acetate ion. Other complexes are also of monomer structure. Azomethines (HL1-9) behave as mono-deprotonated tetradentate O,N,N,O ligands. The thermolysis of substances includes a stage of complete thermal decomposition (360-530 degrees C). Synthesized complexes show selective antimicrobial activity against a series of standard strains of Staphylococcus aureus and E. coli at the concentration in the range of 75-300 mu g ml(-1). DOI: 10.1134/S1070363211090209

  DOI：

  10.1134/s1070363211090209