i-Bu2NCOCH2SOCH2CON-i-Bu2 | 1256086-22-2

• 分子结构分类: 有机化合物 - 有机酸及其衍生物
• 英文名称: i-Bu2NCOCH2SOCH2CON-i-Bu2
• 英文别名: BCMSO
• CAS: 1256086-22-2
• 化学式: C₂₀H₄₀N₂O₃S
• 分子量: 388.615
• InChiKey: MIBVENUDJWWSJD-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  (iso-butyl)2NCOCH2SCH2CON(iso-butyl) 在 selenium(IV) oxide 、 双氧水 作用下， 以 甲醇 为溶剂， 以61%的产率得到i-Bu2NCOCH2SOCH2CON-i-Bu2
  参考文献：
  名称：

  Synthesis and structural studies of a bis(carbamoyl methyl) sulfoxide complex of uranyl nitrate

  摘要：

  A new tri-functional ligand iBu2NCOCH2SOCH2CONiBu2 was prepared and characterized. The coordination chemistry of this ligand with uranyl nitrate was studied with IR, 1H NMR, electrospray mass-spectrometry, thermogravimetry, and elemental analysis. The structure of [UO2(NO3)2(iBu2NCOCH2SOCH2CONiBu2)] was determined by single-crystal X-ray diffraction. The uranium(VI) ion is surrounded by eight oxygens in a hexagonal bipyramidal geometry. Four oxygens from two nitrates and two oxygens from the ligand form a planar hexagon. The ligand is a bidentate chelate, bonding through sulfoxo and one of the carbamoyl groups to uranyl nitrate.

  DOI：

  10.1080/00958972.2010.517269