(E)-5-benzoyl-1-((2,3-dihydroxybenzylidene)amino)-4-phenylpyrimidin-2(1H)-one | 688810-79-9

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: (E)-5-benzoyl-1-((2,3-dihydroxybenzylidene)amino)-4-phenylpyrimidin-2(1H)-one
• CAS: 688810-79-9
• 化学式: C₂₄H₁₇N₃O₄
• 分子量: 411.417
• InChiKey: ZQJKLRGUDCGXAS-AFUMVMLFSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.43
• 重原子数：
  31.0
• 可旋转键数：
  5.0
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  104.78
• 氢给体数：
  2.0
• 氢受体数：
  7.0

反应信息

• 作为反应物：
  描述：

  nickel(II) chloride hexahydrate 、 (E)-5-benzoyl-1-((2,3-dihydroxybenzylidene)amino)-4-phenylpyrimidin-2(1H)-one 以 甲醇 、 氯仿 为溶剂， 以60%的产率得到
  参考文献：
  名称：

  Synthesis and Characterization of Cu(II), Co(II), Ni(II), and Zn(II) Complexes of a Schiff Base Derived from 1‐Amino‐5‐benzoyl‐4‐phenyl‐1H‐pyrimidine‐2‐one and 3‐Hydroxysalicylaldehyde

  摘要：

  Cu(II), Co(II), Ni(II) and Zn(II) metal complexes of a new beterocylic Schiff base derived from 1-amino-5-benzoyl-4-phenyl-1H-pyrimidine-2-one with 3-hydroxy-salicylaidehyde have been synthesized and characterized on the basis of elemental analyses, electronic, IR and H-1 NMR spectra, molar conductivity measurements, magnetic moment measurements and thermogravimetric analyses (TGA). It has been found that the Schiff base behaves as a neutral bidentate (NO) or tridentate (ONO) ligand forming chelates with 1:2 (metal:ligand) stoichiometry and octahedral geometry. The conductivity data for the Ni(II) complex is consistent with that expected for a weak electrolyte.

  DOI：

  10.1081/sim-120026545