[Pt(C6(NO2)2-2,6-(OMe)3-3,4,5-κ2-C,O)(C6(NO2)2-2,6-(OMe)3-3,4,5-κ1-C)(NCPh)] | 727730-63-4

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: [Pt(C6(NO2)2-2,6-(OMe)3-3,4,5-κ2-C,O)(C6(NO2)2-2,6-(OMe)3-3,4,5-κ1-C)(NCPh)]
• 英文别名: cis-[Pt(C6(NO2)2-2,6-(OMe)3-3,4,5-κ2-C,O)(C6(NO2)2-2,6-(OMe)3-3,4,5-κ1-C)(NCPh)]；benzonitrile;platinum(2+);2,3,4-trimethoxy-1,5-dinitrobenzene-6-ide
• CAS: 727730-63-4
• 化学式: C₂₅H₂₃N₅O₁₄Pt
• 分子量: 812.563
• InChiKey: IRCSGXBKOFKXCJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [Pt(C6(NO2)2-2,6-(OMe)3-3,4,5-κ2-C,O)(C6(NO2)2-2,6-(OMe)3-3,4,5-κ1-C)(NCPh)] 、 mercury(II) diacetate 以 二氯甲烷 为溶剂， 以30%的产率得到[Hg(μ-acetato)2(Pt(C6(NO2)2-2,6-(OMe)3-3,4,5-κ2-C,O)2)2]
  参考文献：
  名称：

  Bis(2,6-dinitroaryl)platinum Complexes. 2.¹ Di- and Trinuclear Complexes Containing Pt−Hg Bonds

  摘要：

  [Hg(O2CR)(2)] reacts with an equimolar amount of cis-Me4N[Pt(kappa(2)-Ar)(kappa(1)-Ar)Cl] (1) [kappa(2)-Ar = C-6(NO2)(2)-2,6-(OMe)(3)-3,4,5-kappa(2)-C,O; kappa(1)-Ar = C-6(NO2)(2)-2,6-(OMe)(3)-3,4,5-kappa(1)-C] or with cis-[Pt-(kappa(2) -Ar)(kappa(1)-Ar)(OH2)] (2) in a 2:1 molar ratio to give Me4N[Hg(mu-OAc)(2){Pt(kappa(1)-Ar)(2)Cl}] (5) or, depending on R, [Hg(mu-OAc)(2){Pt(kappa(2)-Ar)(2)}(2)] (6) or [Hg{Pt(kappa(2)-Ar)(2)(O2CR)}(2)] [R = Ar (7), C6F5 (8), CF3 (9)]. Refluxing in toluene a mixture of [HgAr2] [Ar = C-6(NO2)(2)-2,6-(OMe)(3)-3,4,5], [Pt(dba)(2)] (dba = dibenzylideneacetone), and (i) PPh3 (1:1:2) or (ii) bpy in molar ratio 1:1.3: 1.6 gave cis-[Pt(kappa(1)-Ar){Hg(kappa(1)-Ar)}L-2] [L = PPh3 (10), L-2 = bpy (11)]. Complex 10 reacts with XyNC (Xy = C6H3Me2-2,6) to give [Pt(kappa(1)-Ar){Hg(kappa(1)-Ar)}(CNXy)(PPh3)] (12). The structures of complexes 7, 9.CHCl3.CH2Cl2, and 10 have been solved by X-ray diffraction studies.

  DOI：

  10.1021/om049699y
• 作为产物：
  描述：

  cis-[Me4N][Pt(C6(NO2)2-2,6-(OMe)3-3,4,5-κ2-C,O)(C6(NO2)2-2,6-(OMe)3-3,4,5-κ1-C)Cl] 以 乙醚 、 二氯甲烷 为溶剂， 生成 [Pt(C6(NO2)2-2,6-(OMe)3-3,4,5-κ2-C,O)(C6(NO2)2-2,6-(OMe)3-3,4,5-κ1-C)(NCPh)]
  参考文献：
  名称：

  Bis(2,6-dinitroaryl)platinum Complexes. 1. Synthesis through Transmetalation Reactions

  摘要：

  Complexes CiS-Q[Pt(kappa(2)-Ar)(kappa(1)-Ar)Cl] [Q = Ph3PCH2Ph (1), Me4N (2); kappa(2)-Ar = C-6(NO2)(2)-2,6-(OMe)(3)-3,4,5-kappa(2)-C,O; kappa(1)-Ar = C-6(NO2)(2)-2,6-(OMe)(3)-3,4,5- kappa(1)-C] have been prepared by reacting [HgAr2] [Ar = C-6(NO2)(2)-2,6-(OMe)(3)-3,4,5] and Q(2)[Pt2Cl6] (4:1) in acetone at 100 degreesC. Complex 2 could be prepared by reacting [HgAr2] (i) with [Me4N](2)[Pt2Cl6] (2:1) in the presence of an excess of [Me4N]Cl or (ii) with [Me4N](2)[PtCl4] (1:1). The reaction of equimolecular amounts of 2 and Tl(acac) or AgClO4 gave, respectively, cis-Me4N[Pt(kappa(1)-Ar)(2)(acaC-kappa(2_)O,O)] (3) or cis-[Pt(kappa(2)-Ar)(kappa(1)-Ar)(OH2)] (4), which in turn reacts with neutral ligands to give cis-[Pt(kappa(2)-Ar)- (kappa(1)-Ar)L] [L = PhCN (5), tetrahydrothiophene (6)]. Hg(O2CCF3)(2) reacts with an equimolar amount of 2 to give cis-Me4N[Pt(kappa(2)-Ar)(kappa(1)-Ar){OC(O)CF3}] (7). The structures of complexes 1, 4.Et2O, 4.CH2Cl2, and 7 have been solved by X-ray diffraction studies.

  DOI：

  10.1021/om049801r