| 213908-25-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 菲及其衍生物
• CAS: 213908-25-9
• 化学式: C₄₈H₂₈N₈O₂Ru
• 分子量: 849.873
• InChiKey: NLIRJVAIZPEQSU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  [Ru(2,2'-bipyridine)2(5,6-diamino-1,10-phenanthroline)](PF6)2 * 2 H2O 、 芘- 4,5,9,10 -四酮 以 水 、 溶剂黄146 、 乙腈 为溶剂， 以64%的产率得到[(2,2'-bipyridine)2Ru(bis-dipyrido[3,2-f:2',3'-h]quinoxalo-[2,3-e:2',3'-l]pyrene)Ru(2,2'-bipyridine)](PF6)4 * 8 H2O
  参考文献：
  名称：

  Synthesis, Mass Spectrometry, and Spectroscopic Properties of a Dinuclear Ruthenium Complex Comprising a 20 Å Long Fully Aromatic Bridging Ligand

  摘要：

  The luminescent dinuclear ruthenium complex [(bpy)(2)Ru(bqpy)Ru(bpy)(2)](4+) (1) comprising the 20 Angstrom long fully aromatic bridging ligand bqpy has been synthesized by successive reactions from suitable precursor complexes. Investigations in electrospray mass spectrometry and H-1 NMR spectroscopy have indicated the formation of supramolecular aggregates by strong pi-stacking of the large aromatic parts. Despite the extended aromatic character of the bqpy bridging ligand, electrochemical and spectroscopic studies of the dinuclear complex have shown that the complex is composed of four noninteracting parts: two Ru(bpy)(3)(2+)-type units bridged by two bqpy-localized fragments similar to two fused phenazine moieties.

  DOI：

  10.1021/ic9812196