[PtI2M2(1,2-bis(pyrazol-1-yl)ethane)] | 1075255-57-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 唑类
• 英文名称: [PtI2M2(1,2-bis(pyrazol-1-yl)ethane)]
• CAS: 1075255-57-0
• 化学式: C₁₀H₁₆I₂N₄Pt
• 分子量: 641.153
• InChiKey: IGUUTBZPAXEBIR-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  (1,5-cyclooctadiene)dimethylplatinum(II) 、 碘 、 1,2-bis(pyrazol-1-yl)ethane 以 二氯甲烷 为溶剂， 以81%的产率得到[PtI2M2(1,2-bis(pyrazol-1-yl)ethane)]
  参考文献：
  名称：

  Platinum(IV) complexes with α,ω-bis(pyrazol-1-yl) alkanediyl and diethyl ether/thioether ligands. Crystal structures of dibromodimethyl[1,2-bis(pyrazol-1-yl)ethane]platinum(IV) and trimethyl-bis[2-(pyrazol-1-yl)ethyl]etherplatinum(IV) tetrafluoroborate

  摘要：

  Reactions of the flexible alpha,omega-bis(pyrazol-1-yl) compounds 1,2-bis(pyrazol-1-yl)ethane (L1), 1,8-bis(pyrazol-1-yl)-n-octane (L2), bis[2-(pyrazol-1-yl)ethyl]ether (L3) and bis[2-(pyrazol-1-yl)ethyl]thioether(L4) with precursor organometallic platinum complexes ([(PtBr2Me2)(n)], [(PtIMe3)(4)] and [(PtMe2(cod)]/I-2) are described herein. The spectroscopic characterization of the platinum(IV) products of these reactions [PtBr2Me2{pz(CH2)(m)pz}], m = 2 (1) or 8 (2), [PtI2Me2{pz(CH2)(2)pz}] (3), [PtMe3(pzCH(2)CH(2)OCH(2)CH(2)pz)]-[BF4] (4) and [PtMe3(pzCH(2)CH(2)SCH(2)CH(2)pz)][CF3SO3] (5), where 'pz' is pyrazol-1-yl, is discussed. Furthermore, solid state structures of 1, a complex with a seven-membered chelate ring, and 4, a complex bearing the neutral kappa N-2,N ',kappa O ligand bis[2-(pyrazol-1-yl)ethyl]ether (L3) are reported. (C) 2008 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2008.07.003