[Cu(3-amino-5,6-dimethyl-1,2,4-triazine)(AsPh3)2I] | 1562455-14-4

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 唑类
• 英文名称: [Cu(3-amino-5,6-dimethyl-1,2,4-triazine)(AsPh3)2I]
• 英文别名: [Cu(3-amino-5,6-dimethyl-1,2,4-triazine)(AsPh₃)₂I]；[Cu(ADMT)(AsPh₃)₂I]
• CAS: 1562455-14-4
• 化学式: C₄₁H₃₈As₂CuIN₄
• 分子量: 927.073
• InChiKey: IXAKXPNFMDRVRO-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  copper(l) iodide 、 3-氨基-5,6-二甲基-1,2,4-三嗪 、 三苯胂 以 N,N-二甲基甲酰胺 为溶剂， 反应 0.67h， 以34%的产率得到[Cu(3-amino-5,6-dimethyl-1,2,4-triazine)(AsPh3)2I]
  参考文献：
  名称：

  Synthesis and structural characterization of seven copper(I) complexes with 3-amino-5,6-dimethyl-1,2,4-triazine and triphenylphosphine/triphenylarsine

  摘要：

  Seven new copper(I) complexes containing 3-amino-5,6-dimethy1-1,2,4-triazine (ADMT), (Cu(mu-Cl)(ADMT)(PPh3)](2) (1), [Cu(mu-NCs)(ADMT)(PPh3)](2) (2), [Cu(ADMT)(PPh3)(2)Cl] (3), [Cu(ADMT)(PPh3)(2)Br] (4), [Cu(mu-Cl)(ADMT)(AsPh3)](2) (5), [Cu(mu Br)(ADMT)(AsPh3)](2) (6) and [Cu(ADMT)(AsPh3)(2)I] (7) have been synthesized by the reactions of CuX (X = Cl, Br, I, SCN) with triphenylphosphine/triphenylarsine EPh3 (E = P for 1-4; E = As for 5-7) and ADMT in mixed solvents. Complexes 1-7 have been characterized by IR, NMR, luminescence, elemental analyses and X-ray diffraction. In 1, 2, 5 and 6, the intermolecular hydrogen bonds of type I R-2(2)(8) are formed by two N-H donors and two N atoms from two ADMT ligands. In 1-7, the intramolecular hydrogen bond of type II R-1(1)(6) is formed between one N-H donor from ADMT and one halide ion. In 1, 2, 5 and 6, the halide ions and thiocyanate ions bridge two copper atoms to form the parallelogram Cu2X2, which are further linked to form infinite zigzag chains along alpha-axis through the hydrogen bond of type I R-2(2)(8). (C) 2013 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2013.12.026