2,3,5-trimethylthiazolo[4,5-d]thiazolium iodide | 1256262-56-2

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 唑类
• 英文名称: 2,3,5-trimethylthiazolo[4,5-d]thiazolium iodide
• CAS: 1256262-56-2
• 化学式: C₇H₉N₂S₂*I
• 分子量: 312.198
• InChiKey: LAJJOYZLJIYFNZ-UHFFFAOYSA-M

反应信息

• 作为反应物：
  描述：

  2,3,5-trimethylthiazolo[4,5-d]thiazolium iodide 、 对二甲氨基苯甲醛 以 甲醇 为溶剂， 反应 0.25h， 以66%的产率得到
  参考文献：
  名称：

  Thiazolo[4,5-d]thiazole—a new domain for potential optoelectronic application

  摘要：

  A novel heterocyclic moiety based on thiazolo[4.5-d]thiazole was prepared via a six-step synthesis from butane-2,3-dione. This thiazolothiazole compound was further derivatized to afford either neutral conjugated condensation products or analogous N-alkyl salts. The obtained derivatives represent dipolar structures expressed as A-pi-D (push-pull compounds) as well as quadrupolar D-pi-A-pi-D structures. Both types of compound show intramolecular charge transfer and therefore could be suitable for nonlinear optical applications. (C) 2010 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2010.08.110
• 作为产物：
  描述：

  dimethylthiazolo[4,5-d]thiazole 、 碘甲烷 以 甲醇 为溶剂， 100.0 ℃ 、500.01 kPa 条件下， 反应 0.25h， 以97%的产率得到2,3,5-trimethylthiazolo[4,5-d]thiazolium iodide
  参考文献：
  名称：

  Thiazolo[4,5-d]thiazole—a new domain for potential optoelectronic application

  摘要：

  A novel heterocyclic moiety based on thiazolo[4.5-d]thiazole was prepared via a six-step synthesis from butane-2,3-dione. This thiazolothiazole compound was further derivatized to afford either neutral conjugated condensation products or analogous N-alkyl salts. The obtained derivatives represent dipolar structures expressed as A-pi-D (push-pull compounds) as well as quadrupolar D-pi-A-pi-D structures. Both types of compound show intramolecular charge transfer and therefore could be suitable for nonlinear optical applications. (C) 2010 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2010.08.110