Cu(salycilideneanthranilate-H)(2-methylbenzimidazole) | 1018338-60-7

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: Cu(salycilideneanthranilate-H)(2-methylbenzimidazole)
• 英文别名: Cu(SAA)(MebenzImH)
• CAS: 1018338-60-7
• 化学式: C₂₂H₁₇CuN₃O₃
• 分子量: 434.941
• InChiKey: ZGNAVWBDHLEONH-CBNWXSEKSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  2-甲基苯并咪唑 、 copper(II) choride dihydrate 、 potassium salycilideneanthranilate 以 甲醇 为溶剂， 以60%的产率得到Cu(salycilideneanthranilate-H)(2-methylbenzimidazole)
  参考文献：
  名称：

  Synthesis, structure and properties of some copper(II) complexes containing an ONO donor Schiff base and substituted imidazole ligands

  摘要：

  Five new mixed ligand coper(II) complexes, viz. [Cu(SAA)(H2O)] (1), [Cu(SAA)(MeImH)] (2), [Cu(SAA)(EtImH)] (3), [Cu(SAA)-(BenzImH)] (4) and [Cu(SAA)(MebenzImH)] (5), where SAA = salicylideneanthranilic acid, MeImH = 2-methylimidazole, EtImH = 2-ethylimidazole, BenzlmH - benzimidazole, MebenzImH = 2-methylbenzimidazole, have been synthesized and characterized by means of elemental analysis, FAB mass spectrometry, magnetic susceptibility, X-band EPR, electronic spectroscopy, IR and cyclic voltammetry. The frozen solution EPR spectra of the complexes have shown axial features. Single crystal X-ray analysis of 2 and 3 has revealed the presence of a distorted square planar geometry (N2O2) in the complexes. The superoxide dismutase (SOD) activity of the present complexes has also been measured and discussed. (C) 2008 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2007.11.042