[rhodium(I)(cycloocta-1,5-diene)(N(C6H5)CHC3H2N2(CH3))] tetrakis[3,5-bis(trifluoromethyl)phenyl]-borate | 1450619-16-5

• 英文名称: [rhodium(I)(cycloocta-1,5-diene)(N(C6H5)CHC3H2N2(CH3))] tetrakis[3,5-bis(trifluoromethyl)phenyl]-borate
• CAS: 1450619-16-5
• 化学式: C₁₉H₂₃N₃Rh*C₃₂H₁₂BF₂₄
• 分子量: 1259.54
• InChiKey: BPQHYOCATWDIQS-JSHANCFJSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  一氧化碳 、 [rhodium(I)(cycloocta-1,5-diene)(N(C6H5)CHC3H2N2(CH3))] tetrakis[3,5-bis(trifluoromethyl)phenyl]-borate 以 二氯甲烷 为溶剂， 反应 0.25h， 以76%的产率得到[rhodium(I)(carbonyl)2(N(C6H5)CHC3H2N2(CH3))] tetrakis[3,5-bis(trifluoromethyl)phenyl]-borate
  参考文献：
  名称：

  Cooperative Catalysis: Large Rate Enhancements with Bimetallic Rhodium Complexes

  摘要：

  A large increase in reaction rate was observed for the catalyzed mono- and dihydroalkoxylation of alkynes when structurally constrained bimetallic Rh(I) catalysts with imidazolyl-imine ligands were compared to their monometallic analogues. The "cooperative" enhancement was vastly improved by restricting the conformational freedom of the bimetallic structure and minimizing the intermetallic Rh center dot center dot center dot Rh distance.

  DOI：

  10.1021/om400613b
• 作为产物：
  描述：

  [Rh(cod)2]BARF 、 1-(1-methylimidazol-2-yl)-N-phenylmethanimine 以 四氢呋喃 为溶剂， 反应 2.0h， 以89%的产率得到[rhodium(I)(cycloocta-1,5-diene)(N(C6H5)CHC3H2N2(CH3))] tetrakis[3,5-bis(trifluoromethyl)phenyl]-borate
  参考文献：
  名称：

  Cooperative Catalysis: Large Rate Enhancements with Bimetallic Rhodium Complexes

  摘要：

  A large increase in reaction rate was observed for the catalyzed mono- and dihydroalkoxylation of alkynes when structurally constrained bimetallic Rh(I) catalysts with imidazolyl-imine ligands were compared to their monometallic analogues. The "cooperative" enhancement was vastly improved by restricting the conformational freedom of the bimetallic structure and minimizing the intermetallic Rh center dot center dot center dot Rh distance.

  DOI：

  10.1021/om400613b