2-(4-(6-bromohexyloxy)styryl)pyridine | 1257420-03-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: 2-(4-(6-bromohexyloxy)styryl)pyridine
• CAS: 1257420-03-3
• 化学式: C₁₉H₂₂BrNO
• 分子量: 360.294
• InChiKey: UQMKMJPVGPXWAO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.59
• 重原子数：
  22.0
• 可旋转键数：
  9.0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.32
• 拓扑面积：
  22.12
• 氢给体数：
  0.0
• 氢受体数：
  2.0

反应信息

• 作为反应物：
  描述：

  4-(BOC-氨基)酚 、 2-(4-(6-bromohexyloxy)styryl)pyridine 在 potassium carbonate 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 以80%的产率得到t-butyl 4-(6-(4-(2-(2-pyridinyl)vinyl)phenoxy)hexyloxy)phenylcarbamate
  参考文献：
  名称：

  Comparative Syntheses of Arylamine Monomer with Styrylpyridyl Photo-Crosslinker of Polyarylamine for OLED Hole-Injection Material

  摘要：

  A new arylamine monomer with photo-crosslinkable styrylpyridinyl moiety of conjugated polyarylamine for OLED hole injection material was synthesized through two synthetic routes, BOC-amine protection/deprotection and nitro group reduction methods. Both synthetic routes yielded practically pure amine product by standard aqueous workup and crystallization in 61% overall yield from pyridinylvinylphenol 2. Their reaction efficiencies were comparatively studied in views of practicality and reaction scale. Also, the synthetic conditions of key compound of photo-crosslinker, pyridinylvinylphenol 2 was reinvestigated and established for the reproducible and reliable preparation.

  DOI：

  10.1080/15421406.2010.499316
• 作为产物：
  描述：

  碳酸甲丙酯 在 potassium carbonate 、 溶剂黄146 、 potassium hydroxide 作用下， 以 乙醇 、 水 、 N,N-二甲基甲酰胺 为溶剂， 反应 36.5h， 生成 2-(4-(6-bromohexyloxy)styryl)pyridine
  参考文献：
  名称：

  Comparative Syntheses of Arylamine Monomer with Styrylpyridyl Photo-Crosslinker of Polyarylamine for OLED Hole-Injection Material

  摘要：

  A new arylamine monomer with photo-crosslinkable styrylpyridinyl moiety of conjugated polyarylamine for OLED hole injection material was synthesized through two synthetic routes, BOC-amine protection/deprotection and nitro group reduction methods. Both synthetic routes yielded practically pure amine product by standard aqueous workup and crystallization in 61% overall yield from pyridinylvinylphenol 2. Their reaction efficiencies were comparatively studied in views of practicality and reaction scale. Also, the synthetic conditions of key compound of photo-crosslinker, pyridinylvinylphenol 2 was reinvestigated and established for the reproducible and reliable preparation.

  DOI：

  10.1080/15421406.2010.499316