methacrylic acid-(1-butoxy-ethyl ester) | 85997-75-7

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: methacrylic acid-(1-butoxy-ethyl ester)
• 英文别名: 1-Butoxy-1-methacryloyloxy-aethan；Methacrylsaeure-(1-butoxy-aethylester)；butoxyethyl methacrylate；1-Butoxyethyl methacrylate；1-butoxyethyl 2-methylprop-2-enoate
• CAS: 85997-75-7
• 化学式: C₁₀H₁₈O₃
• 分子量: 186.251
• InChiKey: XXNDEOCNKXHSGK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.1
• 重原子数：
  13
• 可旋转键数：
  7
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.7
• 拓扑面积：
  35.5
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  methacrylic acid-(1-butoxy-ethyl ester) 、 甲基丙烯酸苄基酯 、 甲基丙烯酸 、 2,2'-Azobis(methyl 2-methylpropanate) 在 氮 、 丙二醇甲醚醋酸酯 作用下， 以 正庚烷 、 4-甲基-2-戊酮 为溶剂， 反应 6.0h， 以to obtain Polymer A1-1 (1-n-butoxyethyl methacrylate/benzyl methacrylate/methacrylic acid) as a propylene glycol monomethyl ether acetate solution的产率得到1-n-Butoxyethyl methacrylate benzyl methacrylate methacrylic acid
  参考文献：
  名称：

  Positive photosensitive resin composition and cured film forming method using the same

  摘要：

  提供了一种优异的感光树脂组合物，具有灵敏度、膜残留率和储存稳定性，包括一种含有特定丙烯酸基组分单元的树脂，该单元能够解离酸解离基产生羧基，该树脂在碱性条件下不溶或微溶，当酸解离基解离时变得可溶于碱性条件下，还包括一种含有功能基团的组分单元的树脂，该功能基团能够与羧基反应形成共价键，以及一种在受到光线或辐射照射时能够产生酸的化合物；还提供了使用该正感光树脂组合物形成固化膜的方法，以及一种优异的耐热性、附着力、透光性等性能的固化膜。

  公开号：

  US09034440B2
• 作为产物：
  描述：

  乙烯基正丁醚 、 甲基丙烯酸 在 methacrylic acid-(1-butoxy-ethyl ester) 作用下， 以The structure of the product, 1-n-butoxyethyl methacrylate (Compound C) was obtained in 88% yield的产率得到methacrylic acid-(1-butoxy-ethyl ester)
  参考文献：
  名称：

  Multi-functional alpha-alkoxyalkyl acrylate and methacrylate ester compositions and reworkable polymers formed therefrom

  摘要：

  本发明揭示了包括丙烯酸酯、其聚合物和自由基引发剂在内的粘合剂组合物。该组合物包括多功能α-烷氧基烷基（甲基）丙烯酸酯化合物和自由基引发剂。多功能α-烷氧基烷基（甲基）丙烯酸酯化合物是以下反应产物：（a）具有自由羧酸基的（甲基）丙烯酸或（甲基）丙烯酸酯；和（b）包括两个或更多个1-烯基醚基团且不含缩醛和缩酮基团的化合物，或不含缩醛和缩酮基团且包括一个或多个1-烯基醚基团和一个（甲基）丙烯酸酯基团的化合物。该组合物比传统的丙烯酸酯组合物更容易、更便宜地制备，并在接触酸性介质或加热时降解。该组合物可用于广泛的应用，并与传统的粘合剂添加剂兼容。

  公开号：

  US07067601B2
• 作为试剂：
  描述：

  乙烯基正丁醚 、 甲基丙烯酸 在 methacrylic acid-(1-butoxy-ethyl ester) 作用下， 以The structure of the product, 1-n-butoxyethyl methacrylate (Compound C) was obtained in 88% yield的产率得到methacrylic acid-(1-butoxy-ethyl ester)
  参考文献：
  名称：

  Multi-functional alpha-alkoxyalkyl acrylate and methacrylate ester compositions and reworkable polymers formed therefrom

  摘要：

  本发明揭示了包括丙烯酸酯、它们的聚合物和自由基引发剂的粘合剂组合物。该组合物包括多功能α-烷氧基烷基（甲基）丙烯酸酯化合物和自由基引发剂。多功能α-烷氧基烷基（甲基）丙烯酸酯化合物是以下反应产物：（a）自由羧酸基的（甲基）丙烯酸或（甲基）丙烯酸酯；和（b）包括两个或更多1-烯基醚基团且不含缩醛和缩酮基团的化合物，或不含缩醛和缩酮基团且包括一个或多个1-烯基醚基团和（甲基）丙烯酸酯基团的化合物。该组合物比传统的丙烯酸酯组合物更易于制备，成本更低，并在接触酸性介质或加热时降解。该组合物在广泛的应用中非常有用，并且与传统的粘合剂添加剂兼容。

  公开号：

  US20050101689A1

文献信息

• PHOTOSENSITIVE RESIN COMPOSITION, OXIME SULFONATE COMPOUND, METHOD FOR FORMING CURED FILM, CURED FILM, ORGANIC EL DISPLAY DEVICE, AND LIQUID CRYSTAL DISPLAY DEVICE
  申请人：FUJIFILM Corporation

  公开号：US20130171415A1

  公开（公告）日：2013-07-04

  Disclosed is a photosensitive resin composition comprising: (Component A) an oxime sulfonate compound represented by Formula (1); (Component B) a resin comprising a constituent unit having an acid-decomposable group that is decomposed by an acid to form a carboxyl group or a phenolic hydroxy group; and (Component C) a solvent wherein in Formula (1) R 1 denotes an alkyl group, an aryl group, or a heteroaryl group, each R 2 independently denotes a hydrogen atom, an alkyl group, an aryl group, or a halogen atom, Ar 1 denotes an o-arylene group or an o-heteroarylene group, X denotes O or S, and n denotes 1 or 2, provided that of two or more R 2 s present in the compound, at least one denotes an alkyl group, an aryl group, or a halogen atom.

  揭示了一种光敏树脂组合物，包括：（组分A）由式（1）表示的肟磺酸盐化合物；（组分B）包括具有可被酸分解的基团的树脂，该基团通过酸分解形成羧基或酚羟基；和（组分C）溶剂 其中在式（1）中，R1表示烷基、芳基或杂芳基，每个R2独立地表示氢原子、烷基、芳基或卤素原子，Ar1表示邻芳撑基或邻杂芳撑基，X表示O或S，n表示1或2，前提是在化合物中存在两个或两个以上的R2时，至少有一个表示烷基、芳基或卤素原子。
• BORATE-BASED BASE GENERATOR, AND BASE-REACTIVE COMPOSITION COMPRISING SUCH BASE GENERATOR
  申请人：WAKO PURE CHEMICAL INDUSTRIES, LTD.

  公开号：US20160340374A1

  公开（公告）日：2016-11-24

  An object of the present invention is to provide a compound which is capable of attaining a composition having high storage stability without reacting with a base-reactive compound, even in the case of storage for a long period of time in a mixed state with the base-reactive compound, such as an epoxy-based compound, as well as capable of generating a strong base (guanidines, biguanides, phosphazenes or phosphoniums) by irradiation of light (active energy rays) or heating; a base generator comprising the compound; and a base-reactive composition comprising the base generator and the base-reactive compound. The present invention relates to the compound represented by the general formula (A); the base generator comprising the compound; and the base-reactive composition comprising the base generator and the base-reactive compound. (wherein R 1 represents an alkyl group; an arylalkynyl group which may be substituted with a halogen atom, an alkyl group, an alkoxy group, or an alkylthio group; an alkenyl group; a 2-furylethynyl group; a 2-thiophenylethynyl group; or a 2,6-dithianyl group; R 2 to R 4 each independently represent an alkyl group; an arylalkynyl group which may be substituted with a halogen atom, an alkyl group, an alkoxy group, or an alkylthio group; the aryl group which may be substituted with a halogen atom, an alkyl group, an alkoxy group, or an alkylthio group; a furanyl group; a thienyl group; or an N-alkyl-substituted pyrrolyl group; Z + represents an ammonium cation having a guanidinium group, a biguanidium group or a phosphazenium group, or a phosphonium cation.)

  本发明的目的是提供一种化合物，能够在与碱反应性化合物混合状态长时间存储的情况下，仍能获得具有高储存稳定性的组合物，而不与碱反应性化合物发生反应，同时还能通过光照（活性能量射线）或加热产生强碱（胍胺、双胍胺、磷氮烷或磷銨）；包括该化合物的碱发生器；以及包括该碱发生器和碱反应性化合物的碱反应性组合物。本发明涉及由通式（A）表示的化合物；包括该化合物的碱发生器；以及包括该碱发生器和碱反应性化合物的碱反应性组合物。（其中R1代表烷基；可能被卤素原子、烷基、烷氧基或烷硫基取代的芳基炔基；烯基；2-呋喃基炔基；2-噻吩基炔基；或2,6-二硫基基；R2到R4各自独立地代表烷基；可能被卤素原子、烷基、烷氧基或烷硫基取代的芳基炔基；可能被卤素原子、烷基、烷氧基或烷硫基取代的芳基；呋喃基；噻吩基；或N-烷基取代的吡咯基；Z+代表具有胍胺基团、双胍胺基团或磷氮烷基团的铵阳离子，或磷銨阳离子。）
• [EN] LATENT ACIDS AND THEIR USE<br/>[FR] ACIDES LATENTS ET LEUR UTILISATION
  申请人：BASF SE

  公开号：WO2016124493A1

  公开（公告）日：2016-08-11

  Compounds of the formula (I) and (IA) wherein X is -O(CO)-; R1 is C1-C12haloalkyl or C6-C10haloaryl; R2 is located in position 7 of the coumarinyl ring and is OR8; R2a, R2b and R2C independently of each other are hydrogen; R3 is C1-C8haloalkyl or C1-C8haloalkyl; R4 is hydrogen; and R8 is C1-C6alkyI; are suitable as photosensitive acid donors in the preparation of photoresist compositions such as used for example in the preparation of spacers, insulating layers, interlayer dielectric films, insulation layers, planarization layers, protecting layers, overcoat layers, banks for electroluminescence displays and liquid crystal displays (LCD).

  化合物的化学式（I）和（IA），其中X为-O(CO)-；R1为C1-C12卤代烷基或C6-C10卤代芳基；R2位于香豆素环的第7位，为OR8；R2a、R2b和R2C彼此独立地为氢；R3为C1-C8卤代烷基或C1-C8卤代烷基；R4为氢；R8为C1-C6烷基，适用于作为感光酸给体，用于制备光刻胶组合物，例如用于制备间隔层、绝缘层、层间介质膜、绝缘层、平坦化层、保护层、覆盖层、电致发光显示器和液晶显示器（LCD）的制备。
• ACID-RESISTANT BASE AND/OR RADICAL GENERATOR, AND CURABLE RESIN COMPOSITION CONTAINING SAID BASE AND/OR RADICAL GENERATOR
  申请人：WAKO PURE CHEMICAL INDUSTRIES, LTD.

  公开号：US20190002403A1

  公开（公告）日：2019-01-03

  The present invention relates to a compound represented by the general formula (A), a base- and/or radical-generating agent comprising the compound, and so on. In the formula, four pieces of R 1 each independently represents a hydrogen atom or a fluorine atom; four pieces of R 2 each independently represent a fluorine atom or a trifluoromethyl group; R 3 , R 6 , R 7 and R 10 each independently represent a hydrogen atom or an alkyl group having 1 to 12 carbon atoms; R 4 and R 5 each independently represent a hydrogen atom or an alkyl group having 1 to 12 carbon atoms, or R 4 and R 5 are bonded to each other to represent an alkylene group having 2 to 4 carbon atoms; and R 8 and R 9 each independently represent a hydrogen atom, an alkyl group having 1 to 12 carbon atoms, or an aryl group having 6 to 14 carbon atoms and optionally having a substituent selected from the group consisting of an alkyl group having 1 to 6 carbon atoms, an alkoxy group having 1 to 6 carbon atoms, an alkylthio group having 1 to 6 carbon atoms, a dialkylamino group having 2 to 12 carbon atoms, a halogen atom, and a nitro group, or R 8 and R 9 are bonded to each other to represent an alkylene group having 2 to 4 carbon atoms; provided that two or three of the eight groups R 3 to R 10 are each a hydrogen atom, and, in a case where two of the eight groups are each a hydrogen atom, then three to six of the remaining groups are each an alkyl group having 1 to 12 carbon atoms, and, in a case where three of the eight groups are each a hydrogen atom, then four or five of the remaining groups are each an alkyl group having 1 to 12 carbon atoms.

  本发明涉及一种由通式（A）表示的化合物，包括该化合物的生成碱基和/或基团产生剂等。在该式中，四个R1分别独立表示氢原子或氟原子；四个R2分别独立表示氟原子或三氟甲基基团；R3、R6、R7和R10分别独立表示氢原子或具有1至12个碳原子的烷基基团；R4和R5分别独立表示氢原子或具有1至12个碳原子的烷基基团，或者R4和R5相互连接表示具有2至4个碳原子的亚烷基基团；R8和R9分别独立表示氢原子、具有1至12个碳原子的烷基基团或具有6至14个碳原子且可选地具有选自包括具有1至6个碳原子的烷基基团、具有1至6个碳原子的烷氧基团、具有1至6个碳原子的烷硫基团、具有2至12个碳原子的二烷基氨基团、卤素原子和硝基基团的取代基的芳基团，或者R8和R9相互连接表示具有2至4个碳原子的亚烷基基团；前提是八个基团R3至R10中的两个或三个分别是氢原子，并且在其中两个基团分别是氢原子的情况下，其余基团中的三到六个分别是具有1至12个碳原子的烷基基团，而在其中三个基团分别是氢原子的情况下，其余基团中的四个或五个分别是具有1至12个碳原子的烷基基团。
• CATALYST FOR LIVING RADICAL POLYMERIZATION
  申请人：Goto Atsushi

  公开号：US20110275775A1

  公开（公告）日：2011-11-10

  Provided is a catalyst used for a living radical polymerization method, which contains a central element consisting of carbon and at least one halogen atom binding to the central element. Further, a hydrocarbon compound can be used as a catalyst precursor. A monomer having a radical-reactive unsaturated bond is subjected to a radical polymerization reaction in the presence of the catalyst, consequently a polymer having narrow molecular weight distribution can be obtained, and thus the cost of the living radical polymerization can be remarkably reduced. The present invention is significantly more environmentally friendly and economically excellent than conventional living radical polymerization methods, due to advantages such as low toxicity of the catalyst, low amount of the catalyst used, high solubility of the catalyst, mild reaction conditions, and no coloration/no odor (no need of any post-treatments for a molded article), and the like.

  提供的是用于活性自由基聚合方法的催化剂，其包含由碳组成的中心元素，并且至少有一个卤素原子与中心元素结合。此外，碳氢化合物可以用作催化剂前体。在催化剂存在的情况下，将具有自由基反应不饱和键的单体进行自由基聚合反应，因此可以获得具有窄分子量分布的聚合物，从而可以显着降低活性自由基聚合的成本。由于催化剂毒性低、使用量少、催化剂溶解性高、反应条件温和、成品无色无味（无需对成型物进行任何后处理）等优点，本发明比传统的活性自由基聚合方法在环保和经济方面更加优越。